摘要
A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.
源语言 | 英语 |
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页(从-至) | 4246-4250 |
页数 | 5 |
期刊 | Inorganic Chemistry |
卷 | 61 |
期 | 10 |
DOI | |
出版状态 | 已出版 - 14 3月 2022 |