Atom-Economical Thiocyanation-Amination of Alkynes with N-Thiocyanato-Dibenzenesulfonimide

Haopeng Wu; Chukai Shao; Di Wu; Liang Jiang; Hongquan Yin; Fu Xue Chen

doi:10.1021/acs.joc.0c02780

Atom-Economical Thiocyanation-Amination of Alkynes with N-Thiocyanato-Dibenzenesulfonimide

Haopeng Wu, Chukai Shao, Di Wu, Liang Jiang, Hongquan Yin^*, Fu Xue Chen^*

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

21 引用（Scopus）

摘要

A highly regioselective protocol for intermolecular thiocyanation-amination of alkynes by N-thiocyano-dibenzenesulfonimide (NTSI) as the SCN and nitrogen sources has been developed. A C-S bond and C-N bond are simultaneously constructed in only one step. The reaction under simple mild conditions features a broad substrate scope, atom economy, high yields (up to 94%), and excellent functional group tolerance.

源语言	英语
页（从-至）	5327-5335
页数	9
期刊	Journal of Organic Chemistry
卷	86
期	7
DOI	https://doi.org/10.1021/acs.joc.0c02780
出版状态	已出版 - 2 4月 2021

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abstract = "A highly regioselective protocol for intermolecular thiocyanation-amination of alkynes by N-thiocyano-dibenzenesulfonimide (NTSI) as the SCN and nitrogen sources has been developed. A C-S bond and C-N bond are simultaneously constructed in only one step. The reaction under simple mild conditions features a broad substrate scope, atom economy, high yields (up to 94%), and excellent functional group tolerance.",

author = "Haopeng Wu and Chukai Shao and Di Wu and Liang Jiang and Hongquan Yin and Chen, {Fu Xue}",

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AU - Wu, Haopeng

AU - Shao, Chukai

AU - Wu, Di

AU - Jiang, Liang

AU - Yin, Hongquan

AU - Chen, Fu Xue

PY - 2021/4/2

Y1 - 2021/4/2

N2 - A highly regioselective protocol for intermolecular thiocyanation-amination of alkynes by N-thiocyano-dibenzenesulfonimide (NTSI) as the SCN and nitrogen sources has been developed. A C-S bond and C-N bond are simultaneously constructed in only one step. The reaction under simple mild conditions features a broad substrate scope, atom economy, high yields (up to 94%), and excellent functional group tolerance.

AB - A highly regioselective protocol for intermolecular thiocyanation-amination of alkynes by N-thiocyano-dibenzenesulfonimide (NTSI) as the SCN and nitrogen sources has been developed. A C-S bond and C-N bond are simultaneously constructed in only one step. The reaction under simple mild conditions features a broad substrate scope, atom economy, high yields (up to 94%), and excellent functional group tolerance.

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JF - Journal of Organic Chemistry

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ER -

Atom-Economical Thiocyanation-Amination of Alkynes with N-Thiocyanato-Dibenzenesulfonimide

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