Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes

Shao Feng Lu; Da Ming Du; Jiaxi Xu; Shi Wei Zhang

doi:10.1021/ja0604008

Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C₂-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes

Shao Feng Lu, Da Ming Du^*, Jiaxi Xu, Shi Wei Zhang

^*此作品的通讯作者

Peking University

科研成果: 期刊稿件 › 文章 › 同行评审

132 引用（Scopus）

摘要

The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C₂-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).

源语言	英语
页（从-至）	7418-7419
页数	2
期刊	Journal of the American Chemical Society
卷	128
期	23
DOI	https://doi.org/10.1021/ja0604008
出版状态	已出版 - 14 6月 2006
已对外发布	是

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10.1021/ja0604008

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Lu, S. F., Du, D. M., Xu, J., & Zhang, S. W. (2006). Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C₂-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes. Journal of the American Chemical Society, 128(23), 7418-7419. https://doi.org/10.1021/ja0604008

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title = "Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes",

abstract = "The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).",

author = "Lu, {Shao Feng} and Du, {Da Ming} and Jiaxi Xu and Zhang, {Shi Wei}",

year = "2006",

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AU - Lu, Shao Feng

AU - Du, Da Ming

AU - Xu, Jiaxi

AU - Zhang, Shi Wei

PY - 2006/6/14

Y1 - 2006/6/14

N2 - The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).

AB - The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).

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IS - 23

ER -

Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes

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Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C₂-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes