Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer

Hui Zhong Kou; Jun Tao; Osamu Sato

doi:10.1039/b800659h

Assembly of a two-dimensional oxalate-bridged heterometallic Co ^II₃Cr^III₂ coordination polymer

Hui Zhong Kou^*, Jun Tao, Osamu Sato

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摘要

Reaction of CoCl₂•4H₂O with Ag ₃[Cr(ox)₃] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)₂]₃[Cr(ox) ₃]₂•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

源语言	英语
页（从-至）	3652-3656
页数	5
期刊	Dalton Transactions
期	28
DOI	https://doi.org/10.1039/b800659h
出版状态	已出版 - 2008
已对外发布	是

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title = "Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer",

abstract = "Reaction of CoCl2•4H2O with Ag 3[Cr(ox)3] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox) 3]2•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.",

author = "Kou, {Hui Zhong} and Jun Tao and Osamu Sato",

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T1 - Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer

AU - Kou, Hui Zhong

AU - Tao, Jun

AU - Sato, Osamu

PY - 2008

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N2 - Reaction of CoCl2•4H2O with Ag 3[Cr(ox)3] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox) 3]2•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

AB - Reaction of CoCl2•4H2O with Ag 3[Cr(ox)3] (3:mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox) 3]2•6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

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U2 - 10.1039/b800659h

DO - 10.1039/b800659h

M3 - Article

AN - SCOPUS:46949085625

SN - 1477-9226

SP - 3652

EP - 3656

JO - Dalton Transactions

JF - Dalton Transactions

IS - 28

ER -

Assembly of a two-dimensional oxalate-bridged heterometallic Co II3CrIII2 coordination polymer

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Assembly of a two-dimensional oxalate-bridged heterometallic Co ^II₃Cr^III₂ coordination polymer