Anion binding of tris-(thio)urea ligands

Yanlei Zhang; Rui Zhang; Yanxia Zhao; Liguo Ji; Chuandong Jia; Biao Wu

doi:10.1039/c3nj00401e

Anion binding of tris-(thio)urea ligands

Yanlei Zhang, Rui Zhang, Yanxia Zhao, Liguo Ji, Chuandong Jia, Biao Wu^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

13 引用（Scopus）

摘要

Two tridentate tris-(thio)urea ligands (L² and L³) have been synthesized. Ligand L² forms a 2:2 complex (1) with the (H₂PO₄·HPO₄)^3- dimer. ¹H NMR and UV-vis titrations revealed that the mixed urea-thiourea ligand, L², shows considerable anion binding affinities, while the tris-thiourea ligand, L³, undergoes deprotonation in the presence of basic anions.

源语言	英语
页（从-至）	2266-2270
页数	5
期刊	New Journal of Chemistry
卷	37
期	8
DOI	https://doi.org/10.1039/c3nj00401e
出版状态	已出版 - 8月 2013
已对外发布	是

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title = "Anion binding of tris-(thio)urea ligands",

abstract = "Two tridentate tris-(thio)urea ligands (L2 and L3) have been synthesized. Ligand L2 forms a 2:2 complex (1) with the (H2PO4·HPO4)3- dimer. 1H NMR and UV-vis titrations revealed that the mixed urea-thiourea ligand, L2, shows considerable anion binding affinities, while the tris-thiourea ligand, L3, undergoes deprotonation in the presence of basic anions.",

author = "Yanlei Zhang and Rui Zhang and Yanxia Zhao and Liguo Ji and Chuandong Jia and Biao Wu",

year = "2013",

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doi = "10.1039/c3nj00401e",

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T1 - Anion binding of tris-(thio)urea ligands

AU - Zhang, Yanlei

AU - Zhang, Rui

AU - Zhao, Yanxia

AU - Ji, Liguo

AU - Jia, Chuandong

AU - Wu, Biao

PY - 2013/8

Y1 - 2013/8

N2 - Two tridentate tris-(thio)urea ligands (L2 and L3) have been synthesized. Ligand L2 forms a 2:2 complex (1) with the (H2PO4·HPO4)3- dimer. 1H NMR and UV-vis titrations revealed that the mixed urea-thiourea ligand, L2, shows considerable anion binding affinities, while the tris-thiourea ligand, L3, undergoes deprotonation in the presence of basic anions.

AB - Two tridentate tris-(thio)urea ligands (L2 and L3) have been synthesized. Ligand L2 forms a 2:2 complex (1) with the (H2PO4·HPO4)3- dimer. 1H NMR and UV-vis titrations revealed that the mixed urea-thiourea ligand, L2, shows considerable anion binding affinities, while the tris-thiourea ligand, L3, undergoes deprotonation in the presence of basic anions.

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U2 - 10.1039/c3nj00401e

DO - 10.1039/c3nj00401e

M3 - Article

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VL - 37

SP - 2266

EP - 2270

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 8

ER -

Anion binding of tris-(thio)urea ligands

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