An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

Er Rong Wang; Jian Hao Huang; Su Juan Yu; You Zhao Lan; Jian Wen Cheng; Guo Yu Yang

doi:10.1021/acs.inorgchem.7b00975

An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

Er Rong Wang, Jian Hao Huang, Su Juan Yu, You Zhao Lan, Jian Wen Cheng^*, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

Zhejiang Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

46 引用（Scopus）

摘要

Under solvothermal conditions, a chair open-framework borate, Na₂B₉O₁₅(H₂O)(H₃O) (1), has been synthesized. Compound 1 shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different cluster units of B₃O₇ and B₆O₁₃ with three-ring units. The second harmonic generation (SHG) signal intensity of 1 is similar to that of KH₂PO₄ (KDP) and gradually increased with larger particle size. Compound 1 is a potential UV NLO material for its short wavelength absorption edge.

源语言	英语
页（从-至）	6780-6783
页数	4
期刊	Inorganic Chemistry
卷	56
期	12
DOI	https://doi.org/10.1021/acs.inorgchem.7b00975
出版状态	已出版 - 19 6月 2017

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title = "An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units",

abstract = "Under solvothermal conditions, a chair open-framework borate, Na2B9O15(H2O)(H3O) (1), has been synthesized. Compound 1 shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different cluster units of B3O7 and B6O13 with three-ring units. The second harmonic generation (SHG) signal intensity of 1 is similar to that of KH2PO4 (KDP) and gradually increased with larger particle size. Compound 1 is a potential UV NLO material for its short wavelength absorption edge.",

author = "Wang, {Er Rong} and Huang, {Jian Hao} and Yu, {Su Juan} and Lan, {You Zhao} and Cheng, {Jian Wen} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = jun,

day = "19",

doi = "10.1021/acs.inorgchem.7b00975",

language = "English",

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T1 - An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

AU - Wang, Er Rong

AU - Huang, Jian Hao

AU - Yu, Su Juan

AU - Lan, You Zhao

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2017/6/19

Y1 - 2017/6/19

N2 - Under solvothermal conditions, a chair open-framework borate, Na2B9O15(H2O)(H3O) (1), has been synthesized. Compound 1 shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different cluster units of B3O7 and B6O13 with three-ring units. The second harmonic generation (SHG) signal intensity of 1 is similar to that of KH2PO4 (KDP) and gradually increased with larger particle size. Compound 1 is a potential UV NLO material for its short wavelength absorption edge.

AB - Under solvothermal conditions, a chair open-framework borate, Na2B9O15(H2O)(H3O) (1), has been synthesized. Compound 1 shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different cluster units of B3O7 and B6O13 with three-ring units. The second harmonic generation (SHG) signal intensity of 1 is similar to that of KH2PO4 (KDP) and gradually increased with larger particle size. Compound 1 is a potential UV NLO material for its short wavelength absorption edge.

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DO - 10.1021/acs.inorgchem.7b00975

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AN - SCOPUS:85020851514

SN - 0020-1669

VL - 56

SP - 6780

EP - 6783

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

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