摘要
A new 1-D inorganic chain polymer [H2en]4[Hen]2[V6-B 22O53H8]·5H2O, consisting of [V6B20O50H6] cluster subunits linked together through diborate bridges, has been synthesised with high yield and purity by a molten boric acid 'flux' method in which V2O5, en and H3BO3 (1:6:25) were heated together at 180 °C for 3 days; the clusters have a central band of six square-pyramidal VIV=O vanadyl groups, which are capped top and bottom by two raft-like polyborate ligands of formula [B10O16H3].
源语言 | 英语 |
---|---|
页(从-至) | 2463-2464 |
页数 | 2 |
期刊 | Chemical Communications |
期 | 22 |
DOI | |
出版状态 | 已出版 - 21 11月 1998 |
已对外发布 | 是 |
指纹
探究 'An organotemplated vanadium(IV) borate polymer from boric acid 'flux' synthesis, [H2en]4[Hen]2[V6B22O 53H8]·5H2O' 的科研主题。它们共同构成独一无二的指纹。引用此
Williams, I. D., Wu, M., Sung, H. H. Y., Zhang, X. X., & Yu, J. (1998). An organotemplated vanadium(IV) borate polymer from boric acid 'flux' synthesis, [H2en]4[Hen]2[V6B22O 53H8]·5H2O. Chemical Communications, (22), 2463-2464. https://doi.org/10.1039/a805908j