An organotemplated vanadium(IV) borate polymer from boric acid 'flux' synthesis, [H2en]4[Hen]2[V6B22O 53H8]·5H2O

Ian D. Williams*, Mingmei Wu, Herman H.Y. Sung, X. X. Zhang, Jihong Yu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

70 引用 (Scopus)

摘要

A new 1-D inorganic chain polymer [H2en]4[Hen]2[V6-B 22O53H8]·5H2O, consisting of [V6B20O50H6] cluster subunits linked together through diborate bridges, has been synthesised with high yield and purity by a molten boric acid 'flux' method in which V2O5, en and H3BO3 (1:6:25) were heated together at 180 °C for 3 days; the clusters have a central band of six square-pyramidal VIV=O vanadyl groups, which are capped top and bottom by two raft-like polyborate ligands of formula [B10O16H3].

源语言英语
页(从-至)2463-2464
页数2
期刊Chemical Communications
22
DOI
出版状态已出版 - 21 11月 1998
已对外发布

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Williams, I. D., Wu, M., Sung, H. H. Y., Zhang, X. X., & Yu, J. (1998). An organotemplated vanadium(IV) borate polymer from boric acid 'flux' synthesis, [H2en]4[Hen]2[V6B22O 53H8]·5H2O. Chemical Communications, (22), 2463-2464. https://doi.org/10.1039/a805908j