An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom

Lanjun Dong; Xiaofang Li; Jie Cao; Wei Chu; Rudan Huang

doi:10.1039/c2dt31896b

An α-Keggin polyoxometalate completely constructed from the late transition metal Co^II as poly atom

Lanjun Dong, Xiaofang Li, Jie Cao, Wei Chu, Rudan Huang^*

^*此作品的通讯作者

Ministry of Education in China

科研成果: 期刊稿件 › 文章 › 同行评审

20 引用（Scopus）

摘要

We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co^II as a poly atom, [Co ₂₀(OH)₂₄(MMT)₁₂(SO₄)](NO ₃)₂·6H₂O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co^II magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

源语言	英语
页（从-至）	1342-1345
页数	4
期刊	Dalton Transactions
卷	42
期	5
DOI	https://doi.org/10.1039/c2dt31896b
出版状态	已出版 - 7 2月 2013
已对外发布	是

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title = "An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom",

abstract = "We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal CoII as a poly atom, [Co 20(OH)24(MMT)12(SO4)](NO 3)2·6H2O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic CoII magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.",

author = "Lanjun Dong and Xiaofang Li and Jie Cao and Wei Chu and Rudan Huang",

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T1 - An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom

AU - Dong, Lanjun

AU - Li, Xiaofang

AU - Cao, Jie

AU - Chu, Wei

AU - Huang, Rudan

PY - 2013/2/7

Y1 - 2013/2/7

N2 - We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal CoII as a poly atom, [Co 20(OH)24(MMT)12(SO4)](NO 3)2·6H2O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic CoII magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

AB - We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal CoII as a poly atom, [Co 20(OH)24(MMT)12(SO4)](NO 3)2·6H2O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic CoII magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

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DO - 10.1039/c2dt31896b

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VL - 42

SP - 1342

EP - 1345

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom

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An α-Keggin polyoxometalate completely constructed from the late transition metal Co^II as poly atom