TY - JOUR
T1 - Ag@AgHPW as a plasmonic catalyst for visible-light photocatalytic degradation of environmentally harmful organic pollutants
AU - Zhou, Wenhui
AU - Cao, Minhua
AU - Li, Na
AU - Su, Shuangyue
AU - Zhao, Xinyu
AU - Wang, Jiangqiang
AU - Li, Xianghua
AU - Hu, Changwen
PY - 2013/6
Y1 - 2013/6
N2 - Ag@AgxH3-xPW12O40 (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant. They show strong absorption in the visible region because of the localized surface plasmon resonance (LSPR) of Ag NPs. This plasmonic photocatalyst shows a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation, which could be attributed to the highly synergy of photoexcited AgxH3-xPW 12O40 (AgHPW) and plasmon-excited Ag NPs and the confinement effects at interfaces between polyoxometalates (POMs) and silver. POM anions have redox ability and high photocatalytic activity, whereas Ag NPs could effectively accelerate the separation of electrons and holes, both of which contribute to their high activity.
AB - Ag@AgxH3-xPW12O40 (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant. They show strong absorption in the visible region because of the localized surface plasmon resonance (LSPR) of Ag NPs. This plasmonic photocatalyst shows a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation, which could be attributed to the highly synergy of photoexcited AgxH3-xPW 12O40 (AgHPW) and plasmon-excited Ag NPs and the confinement effects at interfaces between polyoxometalates (POMs) and silver. POM anions have redox ability and high photocatalytic activity, whereas Ag NPs could effectively accelerate the separation of electrons and holes, both of which contribute to their high activity.
KW - A. Composites
KW - B. Chemical synthesis
KW - D. Catalytic properties
UR - http://www.scopus.com/inward/record.url?scp=84875921096&partnerID=8YFLogxK
U2 - 10.1016/j.materresbull.2013.02.084
DO - 10.1016/j.materresbull.2013.02.084
M3 - Article
AN - SCOPUS:84875921096
SN - 0025-5408
VL - 48
SP - 2308
EP - 2316
JO - Materials Research Bulletin
JF - Materials Research Bulletin
IS - 6
ER -