Ag@AgHPW as a plasmonic catalyst for visible-light photocatalytic degradation of environmentally harmful organic pollutants

Wenhui Zhou, Minhua Cao*, Na Li, Shuangyue Su, Xinyu Zhao, Jiangqiang Wang, Xianghua Li, Changwen Hu

*此作品的通讯作者

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摘要

Ag@AgxH3-xPW12O40 (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant. They show strong absorption in the visible region because of the localized surface plasmon resonance (LSPR) of Ag NPs. This plasmonic photocatalyst shows a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation, which could be attributed to the highly synergy of photoexcited AgxH3-xPW 12O40 (AgHPW) and plasmon-excited Ag NPs and the confinement effects at interfaces between polyoxometalates (POMs) and silver. POM anions have redox ability and high photocatalytic activity, whereas Ag NPs could effectively accelerate the separation of electrons and holes, both of which contribute to their high activity.

源语言英语
页(从-至)2308-2316
页数9
期刊Materials Research Bulletin
48
6
DOI
出版状态已出版 - 6月 2013

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Zhou, W., Cao, M., Li, N., Su, S., Zhao, X., Wang, J., Li, X., & Hu, C. (2013). Ag@AgHPW as a plasmonic catalyst for visible-light photocatalytic degradation of environmentally harmful organic pollutants. Materials Research Bulletin, 48(6), 2308-2316. https://doi.org/10.1016/j.materresbull.2013.02.084