Aerobic oxidative C-H phosphorylation of quinoxalines under catalyst-free conditions

Qiaoyu Gan; Haibo Liu; Zeqi Jiang; Junmei Xia; Zhenhua Gao; Yongbiao Guo; Hongliang Wen

doi:10.1039/d3cc02848h

Aerobic oxidative C-H phosphorylation of quinoxalines under catalyst-free conditions

Qiaoyu Gan, Haibo Liu, Zeqi Jiang, Junmei Xia, Zhenhua Gao^*, Yongbiao Guo^*, Hongliang Wen^*

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

We herein report a direct and efficient protocol for phosphorylation of quinoxalines, which employs aerobic oxygen as the green oxidant under catalyst-free conditions. This methodology represents one of the most environmentally friendly and easily handled protocols, providing a series of phosphorylated quinoxalines in good to excellent yields. Control experiments clearly indicated that the reaction followed a dearomatization-rearomatization strategy.

源语言	英语
页（从-至）	11089-11092
页数	4
期刊	Chemical Communications
卷	59
期	74
DOI	https://doi.org/10.1039/d3cc02848h
出版状态	已出版 - 21 8月 2023

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Gan, Q., Liu, H., Jiang, Z., Xia, J., Gao, Z., Guo, Y., & Wen, H. (2023). Aerobic oxidative C-H phosphorylation of quinoxalines under catalyst-free conditions. Chemical Communications, 59(74), 11089-11092. https://doi.org/10.1039/d3cc02848h

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abstract = "We herein report a direct and efficient protocol for phosphorylation of quinoxalines, which employs aerobic oxygen as the green oxidant under catalyst-free conditions. This methodology represents one of the most environmentally friendly and easily handled protocols, providing a series of phosphorylated quinoxalines in good to excellent yields. Control experiments clearly indicated that the reaction followed a dearomatization-rearomatization strategy.",

author = "Qiaoyu Gan and Haibo Liu and Zeqi Jiang and Junmei Xia and Zhenhua Gao and Yongbiao Guo and Hongliang Wen",

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T1 - Aerobic oxidative C-H phosphorylation of quinoxalines under catalyst-free conditions

AU - Gan, Qiaoyu

AU - Liu, Haibo

AU - Jiang, Zeqi

AU - Xia, Junmei

AU - Gao, Zhenhua

AU - Guo, Yongbiao

AU - Wen, Hongliang

PY - 2023/8/21

Y1 - 2023/8/21

N2 - We herein report a direct and efficient protocol for phosphorylation of quinoxalines, which employs aerobic oxygen as the green oxidant under catalyst-free conditions. This methodology represents one of the most environmentally friendly and easily handled protocols, providing a series of phosphorylated quinoxalines in good to excellent yields. Control experiments clearly indicated that the reaction followed a dearomatization-rearomatization strategy.

AB - We herein report a direct and efficient protocol for phosphorylation of quinoxalines, which employs aerobic oxygen as the green oxidant under catalyst-free conditions. This methodology represents one of the most environmentally friendly and easily handled protocols, providing a series of phosphorylated quinoxalines in good to excellent yields. Control experiments clearly indicated that the reaction followed a dearomatization-rearomatization strategy.

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SN - 1359-7345

VL - 59

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EP - 11092

JO - Chemical Communications

JF - Chemical Communications

IS - 74

ER -

Aerobic oxidative C-H phosphorylation of quinoxalines under catalyst-free conditions

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