摘要
A cancrinite type aluminoborate with gigantic 24-ring channels has been made under solvothermal conditions using Al(i-PrO)3 as the Al source and amines as the structure directing agents. Its framework is alternately constructed from B5O10 clusters and AlO4 units, no Al-O-Al linkages exist in the structure. Notably, the wall of the 24-ring channels has odd 11-ring windows, resulting in an unprecedented 3D intersecting channel system.
源语言 | 英语 |
---|---|
页(从-至) | 1729-1732 |
页数 | 4 |
期刊 | Chemical Communications |
卷 | 52 |
期 | 8 |
DOI | |
出版状态 | 已出版 - 2016 |