摘要
Two isostructural 1D compounds {[M3(hpdc)2(H 2O)6]·2H2O}n (M = Mn, Co; H3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field-induced magnetic phase transition.
源语言 | 英语 |
---|---|
页(从-至) | 371-373 |
页数 | 3 |
期刊 | Chemical Communications |
期 | 3 |
DOI | |
出版状态 | 已出版 - 2008 |
已对外发布 | 是 |