A two-dimensional (4,4)-network built by tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different Ni-organoamine complexes

Ya Xin Li; Zhong Zhang; Bai Feng Yang; Xin Xiong Li; Qiang Zhang; Guo Yu Yang

doi:10.1016/j.inoche.2016.11.016

A two-dimensional (4,4)-network built by tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different Ni-organoamine complexes

Ya Xin Li, Zhong Zhang, Bai Feng Yang, Xin Xiong Li^*, Qiang Zhang, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

A novel inorganic-organic hybrid polyoxotungstate H₄[Ni(en)₂]₂[Ni(en)(dap)]₂[Ni(dap)₂]₂[Ni₄(en₂)(PW₉O₃₄)₂]-{[Ni(H₂O)₅]₂[Ni₄(en)₂(PW₉O₃₄)₂]}·12H₂O (1, en = ethylenediamine, dap = 1,2-diaminopropane) has been successfully synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis, respectively. Single-crystal structure analysis reveals that 1 exhibits a 2-D network structure based on two kinds of tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different types of Ni-organoamine complexes.

源语言	英语
页（从-至）	12-15
页数	4
期刊	Inorganic Chemistry Communications
卷	75
DOI	https://doi.org/10.1016/j.inoche.2016.11.016
出版状态	已出版 - 1 1月 2017

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10.1016/j.inoche.2016.11.016

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@article{162a75547d284b088fbd64c9fc8b0b46,

title = "A two-dimensional (4,4)-network built by tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different Ni-organoamine complexes",

abstract = "A novel inorganic-organic hybrid polyoxotungstate H4[Ni(en)2]2[Ni(en)(dap)]2[Ni(dap)2]2[Ni4(en2)(PW9O34)2]-{[Ni(H2O)5]2[Ni4(en)2(PW9O34)2]}·12H2O (1, en = ethylenediamine, dap = 1,2-diaminopropane) has been successfully synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis, respectively. Single-crystal structure analysis reveals that 1 exhibits a 2-D network structure based on two kinds of tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different types of Ni-organoamine complexes.",

keywords = "Hydrothermal synthesis, Nickel complex, Polyoxometalate, Sandwich-type structure",

author = "Li, {Ya Xin} and Zhong Zhang and Yang, {Bai Feng} and Li, {Xin Xiong} and Qiang Zhang and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

month = jan,

day = "1",

doi = "10.1016/j.inoche.2016.11.016",

language = "English",

volume = "75",

pages = "12--15",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A two-dimensional (4,4)-network built by tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different Ni-organoamine complexes

AU - Li, Ya Xin

AU - Zhang, Zhong

AU - Yang, Bai Feng

AU - Li, Xin Xiong

AU - Zhang, Qiang

AU - Yang, Guo Yu

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A novel inorganic-organic hybrid polyoxotungstate H4[Ni(en)2]2[Ni(en)(dap)]2[Ni(dap)2]2[Ni4(en2)(PW9O34)2]-{[Ni(H2O)5]2[Ni4(en)2(PW9O34)2]}·12H2O (1, en = ethylenediamine, dap = 1,2-diaminopropane) has been successfully synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis, respectively. Single-crystal structure analysis reveals that 1 exhibits a 2-D network structure based on two kinds of tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different types of Ni-organoamine complexes.

AB - A novel inorganic-organic hybrid polyoxotungstate H4[Ni(en)2]2[Ni(en)(dap)]2[Ni(dap)2]2[Ni4(en2)(PW9O34)2]-{[Ni(H2O)5]2[Ni4(en)2(PW9O34)2]}·12H2O (1, en = ethylenediamine, dap = 1,2-diaminopropane) has been successfully synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis, respectively. Single-crystal structure analysis reveals that 1 exhibits a 2-D network structure based on two kinds of tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different types of Ni-organoamine complexes.

KW - Hydrothermal synthesis

KW - Nickel complex

KW - Polyoxometalate

KW - Sandwich-type structure

UR - http://www.scopus.com/inward/record.url?scp=85002050672&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.11.016

DO - 10.1016/j.inoche.2016.11.016

M3 - Article

AN - SCOPUS:85002050672

SN - 1387-7003

VL - 75

SP - 12

EP - 15

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A two-dimensional (4,4)-network built by tetra-Ni-substituted sandwich-type Keggin polyoxoanions linked by different Ni-organoamine complexes

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