A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

Jin Tang Li; Jun Tao; Rong Bin Huang; Lan Sun Zheng; Tan Yuen; C. L. Lin; Princy Varughese; Jing Li

doi:10.1021/ic050043m

A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

Jin Tang Li, Jun Tao^*, Rong Bin Huang, Lan Sun Zheng, Tan Yuen, C. L. Lin, Princy Varughese, Jing Li

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科研成果: 期刊稿件 › 文章 › 同行评审

28 引用（Scopus）

摘要

A three-dimensional coordination polymer, [Mn₃(OH) ₂Na₂(3-cnba)₆]_n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl₂, NaN₃, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

源语言	英语
页（从-至）	4448-4450
页数	3
期刊	Inorganic Chemistry
卷	44
期	13
DOI	https://doi.org/10.1021/ic050043m
出版状态	已出版 - 27 6月 2005
已对外发布	是

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@article{29567eeae054441093d990b74d12047b,

title = "A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains",

abstract = "A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.",

author = "Li, {Jin Tang} and Jun Tao and Huang, {Rong Bin} and Zheng, {Lan Sun} and Tan Yuen and Lin, {C. L.} and Princy Varughese and Jing Li",

year = "2005",

month = jun,

day = "27",

doi = "10.1021/ic050043m",

language = "English",

volume = "44",

pages = "4448--4450",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

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TY - JOUR

T1 - A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

AU - Li, Jin Tang

AU - Tao, Jun

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Yuen, Tan

AU - Lin, C. L.

AU - Varughese, Princy

AU - Li, Jing

PY - 2005/6/27

Y1 - 2005/6/27

N2 - A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

AB - A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

UR - http://www.scopus.com/inward/record.url?scp=22544466702&partnerID=8YFLogxK

U2 - 10.1021/ic050043m

DO - 10.1021/ic050043m

M3 - Article

AN - SCOPUS:22544466702

SN - 0020-1669

VL - 44

SP - 4448

EP - 4450

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

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