A temperature-responsive C2 wagging vibration in Sc2C2@: C s-C82

Bo Wu; Taishan Wang; Zhuxia Zhang; Li Jiang; Chunru Wang

doi:10.1039/c7cc08509e

A temperature-responsive C₂ wagging vibration in Sc₂C₂@: C _s-C₈₂

Bo Wu, Taishan Wang, Zhuxia Zhang, Li Jiang, Chunru Wang^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The Raman spectra reveal molecular vibration information. Here we report a special temperature-dependent C₂ wagging vibration at 225 cm^-1 in Sc₂C₂@C_s-C₈₂ by Raman spectroscopy and quantum-chemical calculations, which corresponds to the internal cluster motion in C₈₂. This finding is of great importance in understanding the internal dynamics of metallofullerenes.

源语言	英语
页（从-至）	775-777
页数	3
期刊	Chemical Communications
卷	54
期	7
DOI	https://doi.org/10.1039/c7cc08509e
出版状态	已出版 - 2018
已对外发布	是

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title = "A temperature-responsive C2 wagging vibration in Sc2C2@: C s-C82",

abstract = "The Raman spectra reveal molecular vibration information. Here we report a special temperature-dependent C2 wagging vibration at 225 cm-1 in Sc2C2@Cs-C82 by Raman spectroscopy and quantum-chemical calculations, which corresponds to the internal cluster motion in C82. This finding is of great importance in understanding the internal dynamics of metallofullerenes.",

author = "Bo Wu and Taishan Wang and Zhuxia Zhang and Li Jiang and Chunru Wang",

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year = "2018",

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T1 - A temperature-responsive C2 wagging vibration in Sc2C2@

T2 - C s-C82

AU - Wu, Bo

AU - Wang, Taishan

AU - Zhang, Zhuxia

AU - Jiang, Li

AU - Wang, Chunru

N1 - Publisher Copyright: © The Royal Society of Chemistry 2018.

PY - 2018

Y1 - 2018

N2 - The Raman spectra reveal molecular vibration information. Here we report a special temperature-dependent C2 wagging vibration at 225 cm-1 in Sc2C2@Cs-C82 by Raman spectroscopy and quantum-chemical calculations, which corresponds to the internal cluster motion in C82. This finding is of great importance in understanding the internal dynamics of metallofullerenes.

AB - The Raman spectra reveal molecular vibration information. Here we report a special temperature-dependent C2 wagging vibration at 225 cm-1 in Sc2C2@Cs-C82 by Raman spectroscopy and quantum-chemical calculations, which corresponds to the internal cluster motion in C82. This finding is of great importance in understanding the internal dynamics of metallofullerenes.

UR - http://www.scopus.com/inward/record.url?scp=85040928658&partnerID=8YFLogxK

U2 - 10.1039/c7cc08509e

DO - 10.1039/c7cc08509e

M3 - Article

C2 - 29308476

AN - SCOPUS:85040928658

SN - 1359-7345

VL - 54

SP - 775

EP - 777

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

A temperature-responsive C2 wagging vibration in Sc2C2@: C s-C82

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A temperature-responsive C₂ wagging vibration in Sc₂C₂@: C _s-C₈₂