A Novel Vapor-Phase Ssynthetic Route for Fluoromethane toward Highly Efficient Industrial Production

Gang Yang; Chengping Zhang; Hui e. Yang; Hengdao Quan

doi:10.1002/slct.201802562

A Novel Vapor-Phase Ssynthetic Route for Fluoromethane toward Highly Efficient Industrial Production

Gang Yang, Chengping Zhang, Hui e. Yang, Hengdao Quan^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

The preparation of CH₃F via vapor phase catalytic fluorination of CH₃OCH₃ promoted by AlF₃ (H-AlF₃, M-AlF₃, L-AlF₃) with different surface areas was investigated, with the reaction occurring as follows: CH₃OCH₃ +2 HF → 2CH₃F + H₂O. It was found that H-AlF₃ exhibited the highest catalytic activity with high stability among the three types of AlF₃ tested in the 100-h life-span test, which can be attributed to the massive amount of amorphous AlF₃ in H-AlF₃. H-AlF₃ contains the highest amount of acid and largest surface area among the AlF₃ species. The synthetic route of CH₃F showed higher conversion of raw material and better selectivity for CH₃F than traditional routes.

源语言	英语
页（从-至）	527-530
页数	4
期刊	ChemistrySelect
卷	4
期	2
DOI	https://doi.org/10.1002/slct.201802562
出版状态	已出版 - 17 1月 2019
已对外发布	是

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@article{ee64718468f64689a9c4357d3f0f6b00,

title = "A Novel Vapor-Phase Ssynthetic Route for Fluoromethane toward Highly Efficient Industrial Production",

abstract = "The preparation of CH3F via vapor phase catalytic fluorination of CH3OCH3 promoted by AlF3 (H-AlF3, M-AlF3, L-AlF3) with different surface areas was investigated, with the reaction occurring as follows: CH3OCH3 +2 HF → 2CH3F + H2O. It was found that H-AlF3 exhibited the highest catalytic activity with high stability among the three types of AlF3 tested in the 100-h life-span test, which can be attributed to the massive amount of amorphous AlF3 in H-AlF3. H-AlF3 contains the highest amount of acid and largest surface area among the AlF3 species. The synthetic route of CH3F showed higher conversion of raw material and better selectivity for CH3F than traditional routes.",

keywords = "Aluminum fluoride, Catalyst, Dimethyl carbonate, Fluorination, Fluoromethane.",

author = "Gang Yang and Chengping Zhang and Yang, {Hui e.} and Hengdao Quan",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2019",

month = jan,

day = "17",

doi = "10.1002/slct.201802562",

language = "English",

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journal = "ChemistrySelect",

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TY - JOUR

T1 - A Novel Vapor-Phase Ssynthetic Route for Fluoromethane toward Highly Efficient Industrial Production

AU - Yang, Gang

AU - Zhang, Chengping

AU - Yang, Hui e.

AU - Quan, Hengdao

PY - 2019/1/17

Y1 - 2019/1/17

N2 - The preparation of CH3F via vapor phase catalytic fluorination of CH3OCH3 promoted by AlF3 (H-AlF3, M-AlF3, L-AlF3) with different surface areas was investigated, with the reaction occurring as follows: CH3OCH3 +2 HF → 2CH3F + H2O. It was found that H-AlF3 exhibited the highest catalytic activity with high stability among the three types of AlF3 tested in the 100-h life-span test, which can be attributed to the massive amount of amorphous AlF3 in H-AlF3. H-AlF3 contains the highest amount of acid and largest surface area among the AlF3 species. The synthetic route of CH3F showed higher conversion of raw material and better selectivity for CH3F than traditional routes.

AB - The preparation of CH3F via vapor phase catalytic fluorination of CH3OCH3 promoted by AlF3 (H-AlF3, M-AlF3, L-AlF3) with different surface areas was investigated, with the reaction occurring as follows: CH3OCH3 +2 HF → 2CH3F + H2O. It was found that H-AlF3 exhibited the highest catalytic activity with high stability among the three types of AlF3 tested in the 100-h life-span test, which can be attributed to the massive amount of amorphous AlF3 in H-AlF3. H-AlF3 contains the highest amount of acid and largest surface area among the AlF3 species. The synthetic route of CH3F showed higher conversion of raw material and better selectivity for CH3F than traditional routes.

KW - Aluminum fluoride

KW - Catalyst

KW - Dimethyl carbonate

KW - Fluorination

KW - Fluoromethane.

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U2 - 10.1002/slct.201802562

DO - 10.1002/slct.201802562

M3 - Article

AN - SCOPUS:85060211906

SN - 2365-6549

VL - 4

SP - 527

EP - 530

JO - ChemistrySelect

JF - ChemistrySelect

IS - 2

ER -

A Novel Vapor-Phase Ssynthetic Route for Fluoromethane toward Highly Efficient Industrial Production

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