A novel two-dimensional layer structure built from a tetracobalt(II)-p- sulfonatothiacalix[4]arene cluster unit

Daqiang Yuan; Yanqing Xu; Maochun Hong; Wenhua Bi; Youfu Zhou; Xing Li

doi:10.1002/ejic.200400598

A novel two-dimensional layer structure built from a tetracobalt(II)-p- sulfonatothiacalix[4]arene cluster unit

Daqiang Yuan, Yanqing Xu, Maochun Hong^*, Wenhua Bi, Youfu Zhou, Xing Li

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

16 引用（Scopus）

摘要

The novel coordination polymer [Co₄(TCAS)(μ₄- SO₄)(4,4′-Hbipy)₂]_n (TCAS = the octaanion of p-sulfonatothiacalix[4]arene) (1) has been synthesized hydrothermally and characterized. X-ray diffraction analyses reveal a two-dimensional (2D) layer structure built from the [Co₄(TCAS)(μ₄-SO ₄)]²-unit. The tetranuclear cobalt(II) clusters bridged by the μ₄-SO₄^2- and phenoxy groups of the same TCAS provide a unique trapeziform magnetic mode; magnetic studies in the temperature range 2-300 K show weak antiferromagnetic interactions between the four cobalt(II) centers. (

源语言	英语
页（从-至）	1182-1187
页数	6
期刊	European Journal of Inorganic Chemistry
期	6
DOI	https://doi.org/10.1002/ejic.200400598
出版状态	已出版 - 18 3月 2005
已对外发布	是

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title = "A novel two-dimensional layer structure built from a tetracobalt(II)-p- sulfonatothiacalix[4]arene cluster unit",

abstract = "The novel coordination polymer [Co4(TCAS)(μ4- SO4)(4,4′-Hbipy)2]n (TCAS = the octaanion of p-sulfonatothiacalix[4]arene) (1) has been synthesized hydrothermally and characterized. X-ray diffraction analyses reveal a two-dimensional (2D) layer structure built from the [Co4(TCAS)(μ4-SO 4)]2-unit. The tetranuclear cobalt(II) clusters bridged by the μ4-SO42- and phenoxy groups of the same TCAS provide a unique trapeziform magnetic mode; magnetic studies in the temperature range 2-300 K show weak antiferromagnetic interactions between the four cobalt(II) centers. (",

keywords = "Cobalt, Coordination polymer, Magnetic properties, p-Sulfonatothiacalix[4]arene",

author = "Daqiang Yuan and Yanqing Xu and Maochun Hong and Wenhua Bi and Youfu Zhou and Xing Li",

year = "2005",

month = mar,

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doi = "10.1002/ejic.200400598",

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journal = "European Journal of Inorganic Chemistry",

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T1 - A novel two-dimensional layer structure built from a tetracobalt(II)-p- sulfonatothiacalix[4]arene cluster unit

AU - Yuan, Daqiang

AU - Xu, Yanqing

AU - Hong, Maochun

AU - Bi, Wenhua

AU - Zhou, Youfu

AU - Li, Xing

PY - 2005/3/18

Y1 - 2005/3/18

N2 - The novel coordination polymer [Co4(TCAS)(μ4- SO4)(4,4′-Hbipy)2]n (TCAS = the octaanion of p-sulfonatothiacalix[4]arene) (1) has been synthesized hydrothermally and characterized. X-ray diffraction analyses reveal a two-dimensional (2D) layer structure built from the [Co4(TCAS)(μ4-SO 4)]2-unit. The tetranuclear cobalt(II) clusters bridged by the μ4-SO42- and phenoxy groups of the same TCAS provide a unique trapeziform magnetic mode; magnetic studies in the temperature range 2-300 K show weak antiferromagnetic interactions between the four cobalt(II) centers. (

AB - The novel coordination polymer [Co4(TCAS)(μ4- SO4)(4,4′-Hbipy)2]n (TCAS = the octaanion of p-sulfonatothiacalix[4]arene) (1) has been synthesized hydrothermally and characterized. X-ray diffraction analyses reveal a two-dimensional (2D) layer structure built from the [Co4(TCAS)(μ4-SO 4)]2-unit. The tetranuclear cobalt(II) clusters bridged by the μ4-SO42- and phenoxy groups of the same TCAS provide a unique trapeziform magnetic mode; magnetic studies in the temperature range 2-300 K show weak antiferromagnetic interactions between the four cobalt(II) centers. (

KW - Cobalt

KW - Coordination polymer

KW - Magnetic properties

KW - p-Sulfonatothiacalix[4]arene

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U2 - 10.1002/ejic.200400598

DO - 10.1002/ejic.200400598

M3 - Article

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SN - 1434-1948

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 6

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A novel two-dimensional layer structure built from a tetracobalt(II)-p- sulfonatothiacalix[4]arene cluster unit

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