A novel three-dimensional supramolecular framework with one-dimensional channels: Synthesis and crystal structure of [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid)

Li Mao; Yonghui Wang; Yanjuan Qi; Minhua Cao; Changwen Hu

doi:10.1016/j.molstruc.2003.10.015

A novel three-dimensional supramolecular framework with one-dimensional channels: Synthesis and crystal structure of [Cu(DPC)(H₂O) ₃] (H₂DPC=Pyridine-2,6-dicarboxylic acid)

Li Mao, Yonghui Wang, Yanjuan Qi, Minhua Cao, Changwen Hu^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

49 引用（Scopus）

摘要

A new supramolecular compound formulated [Cu(DPC)(H₂O) ₃] (H₂DPC=Pyridine-2,6-dicarboxylic acid) was synthesized under mild conditions and characterized by elemental analyses, IR spectrum, thermogravimetric (TG) analysis and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of C2/c with a=6.4448(9)Å, b=23.192(3)Å, c=6.9139(12)Å, α=90°, β=106.622(11)°, γ=90°, V=990.2(3)Å³, Z=4, R=0.0580, and wR₂=0.1522. The compound exhibits an interesting three-dimensional (3D) supramolecular framework structure with one-dimensional channels, which is constructed by extensive hydrogen-bonding and π-π stacking interactions.

源语言	英语
页（从-至）	197-201
页数	5
期刊	Journal of Molecular Structure
卷	688
期	1-3
DOI	https://doi.org/10.1016/j.molstruc.2003.10.015
出版状态	已出版 - 21 1月 2004
已对外发布	是

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title = "A novel three-dimensional supramolecular framework with one-dimensional channels: Synthesis and crystal structure of [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid)",

abstract = "A new supramolecular compound formulated [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid) was synthesized under mild conditions and characterized by elemental analyses, IR spectrum, thermogravimetric (TG) analysis and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of C2/c with a=6.4448(9){\AA}, b=23.192(3){\AA}, c=6.9139(12){\AA}, α=90°, β=106.622(11)°, γ=90°, V=990.2(3){\AA}3, Z=4, R=0.0580, and wR2=0.1522. The compound exhibits an interesting three-dimensional (3D) supramolecular framework structure with one-dimensional channels, which is constructed by extensive hydrogen-bonding and π-π stacking interactions.",

keywords = "Crystal structure, Hydrogen bonding, One-dimensional channels, Supramolecular framework, π-π stacking interactions",

author = "Li Mao and Yonghui Wang and Yanjuan Qi and Minhua Cao and Changwen Hu",

year = "2004",

month = jan,

day = "21",

doi = "10.1016/j.molstruc.2003.10.015",

language = "English",

volume = "688",

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journal = "Journal of Molecular Structure",

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TY - JOUR

T1 - A novel three-dimensional supramolecular framework with one-dimensional channels

T2 - Synthesis and crystal structure of [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid)

AU - Mao, Li

AU - Wang, Yonghui

AU - Qi, Yanjuan

AU - Cao, Minhua

AU - Hu, Changwen

PY - 2004/1/21

Y1 - 2004/1/21

N2 - A new supramolecular compound formulated [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid) was synthesized under mild conditions and characterized by elemental analyses, IR spectrum, thermogravimetric (TG) analysis and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of C2/c with a=6.4448(9)Å, b=23.192(3)Å, c=6.9139(12)Å, α=90°, β=106.622(11)°, γ=90°, V=990.2(3)Å3, Z=4, R=0.0580, and wR2=0.1522. The compound exhibits an interesting three-dimensional (3D) supramolecular framework structure with one-dimensional channels, which is constructed by extensive hydrogen-bonding and π-π stacking interactions.

AB - A new supramolecular compound formulated [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid) was synthesized under mild conditions and characterized by elemental analyses, IR spectrum, thermogravimetric (TG) analysis and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of C2/c with a=6.4448(9)Å, b=23.192(3)Å, c=6.9139(12)Å, α=90°, β=106.622(11)°, γ=90°, V=990.2(3)Å3, Z=4, R=0.0580, and wR2=0.1522. The compound exhibits an interesting three-dimensional (3D) supramolecular framework structure with one-dimensional channels, which is constructed by extensive hydrogen-bonding and π-π stacking interactions.

KW - Crystal structure

KW - Hydrogen bonding

KW - One-dimensional channels

KW - Supramolecular framework

KW - π-π stacking interactions

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DO - 10.1016/j.molstruc.2003.10.015

M3 - Article

AN - SCOPUS:0842277659

SN - 0022-2860

VL - 688

SP - 197

EP - 201

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

A novel three-dimensional supramolecular framework with one-dimensional channels: Synthesis and crystal structure of [Cu(DPC)(H2O) 3] (H2DPC=Pyridine-2,6-dicarboxylic acid)

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A novel three-dimensional supramolecular framework with one-dimensional channels: Synthesis and crystal structure of [Cu(DPC)(H₂O) ₃] (H₂DPC=Pyridine-2,6-dicarboxylic acid)