A novel synthesis of nitroform by the nitrolysis of cucurbituril

Hong Yan Lu; Jia Rong Li; De Li Yang; Qi Zhang; Da Xin Shi

doi:10.1016/j.cclet.2014.12.019

A novel synthesis of nitroform by the nitrolysis of cucurbituril

Hong Yan Lu, Jia Rong Li, De Li Yang, Qi Zhang, Da Xin Shi^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.

源语言	英语
页（从-至）	365-368
页数	4
期刊	Chinese Chemical Letters
卷	26
期	3
DOI	https://doi.org/10.1016/j.cclet.2014.12.019
出版状态	已出版 - 3月 2015

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10.1016/j.cclet.2014.12.019

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title = "A novel synthesis of nitroform by the nitrolysis of cucurbituril",

abstract = "Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.",

keywords = "Cucurbituril, Homologues, Nitroform, Nitrolysis",

author = "Lu, {Hong Yan} and Li, {Jia Rong} and Yang, {De Li} and Qi Zhang and Shi, {Da Xin}",

year = "2015",

month = mar,

doi = "10.1016/j.cclet.2014.12.019",

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volume = "26",

pages = "365--368",

journal = "Chinese Chemical Letters",

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T1 - A novel synthesis of nitroform by the nitrolysis of cucurbituril

AU - Lu, Hong Yan

AU - Li, Jia Rong

AU - Yang, De Li

AU - Zhang, Qi

AU - Shi, Da Xin

PY - 2015/3

Y1 - 2015/3

N2 - Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.

AB - Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.

KW - Cucurbituril

KW - Homologues

KW - Nitroform

KW - Nitrolysis

UR - http://www.scopus.com/inward/record.url?scp=84940005111&partnerID=8YFLogxK

U2 - 10.1016/j.cclet.2014.12.019

DO - 10.1016/j.cclet.2014.12.019

M3 - Article

AN - SCOPUS:84940005111

SN - 1001-8417

VL - 26

SP - 365

EP - 368

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 3

ER -

A novel synthesis of nitroform by the nitrolysis of cucurbituril

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