A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/ejic.200300601

A novel open-framework zinc phosphite, Zn₃(HPO₃) ₄·Ni(en)₂(H₂O)₂, templated by a transition-metal complex

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

34 引用（Scopus）

摘要

A new three-dimensional zinc phosphite, Zn₃(HPO ₃)₄·Ni(en)₂(H₂O) ₂, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO₄ and HPO₃ units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

源语言	英语
页（从-至）	953-955
页数	3
期刊	European Journal of Inorganic Chemistry
期	5
DOI	https://doi.org/10.1002/ejic.200300601
出版状态	已出版 - 5 3月 2004
已对外发布	是

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title = "A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex",

abstract = "A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.",

keywords = "Inorganic solid, Nickel, Open framework, Template synthesis, Zinc",

author = "Lin, {Zhi En} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

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doi = "10.1002/ejic.200300601",

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AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/3/5

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N2 - A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

AB - A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

KW - Inorganic solid

KW - Nickel

KW - Open framework

KW - Template synthesis

KW - Zinc

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 5

ER -

A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex

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A novel open-framework zinc phosphite, Zn₃(HPO₃) ₄·Ni(en)₂(H₂O)₂, templated by a transition-metal complex