A novel form-stable paraffin-based hydroxyl-terminated polybutadiene binder containing microencapsulated paraffin wax: Preparation, thermal and mechanical properties

Leakage and incompatibility of paraffin wax (PW) in hydroxyl-terminated polybutadiene (HTPB) binders is a major obstacle to its application in polymer-bonded explosives (PBX). In order to solve this issue, we designed a microencapsulated PW (MePW)/PW/HTPB composite in this paper. Melamine–formaldehyde-shelled MePW (MF MePW)/PW/HTPB composites with different contents of MePW and PW were prepared by cast molding method. The chemical composition, crystallinity and microstructure of MePW/PW/HTPB composites were analyzed with Fourier transformed infrared spectroscopy, X-ray diffraction and scanning electron microscope, respectively. The results showed that PW and MF MePW have been uniformly dispersed in HTPB without any chemical interaction. Moreover, differential scanning calorimeter analysis, thermal gravimetric analyzer, thermal cycling test, leaking test, tensile and compressive test were used to investigate the thermal and mechanical properties of these composites. The composites have high latent heat and good thermal reliability. The thermal stability, tensile and compressive strength of MePW/PW/HTPB composites were dramatically increased with the increasing mass fraction of MePW. The introduction of MePW can obviously prevent the leakage of PW in both HTPB binders and PBX. Consequently, it is anticipated that MePW can be used in the next-generation of paraffin-based high-temperature PBX systems.