A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O

Zhong Qiang Zhang; Ru Dan Huang; Yan Qing Xu; Zhi Wei Jiao; Chang Wen Hu

A new method of synthesis for the compound H₂[Hbim]₂ [(Bim)₂Mo₈O₂₆]·H₂O

Zhong Qiang Zhang^*, Ru Dan Huang, Yan Qing Xu, Zhi Wei Jiao, Chang Wen Hu

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

A new compound, H₂[Hbim]₂ [(bim)₂Mo₈O₂₆]·H₂O (bim=benzimidazole), was synthesized by benzimidazole, MoO₃, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm³, Z=2, R₁=0.0525. The compound has the _[Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H⁺ cations play a role of charge-balance.

源语言	英语
页（从-至）	1109-1112
页数	4
期刊	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
卷	28
期	12
出版状态	已出版 - 12月 2008

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@article{457665f8c32f4e3d9aaf0dde65359e79,

title = "A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O",

abstract = "A new compound, H2[Hbim]2 [(bim)2Mo8O26]·H2O (bim=benzimidazole), was synthesized by benzimidazole, MoO3, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm3, Z=2, R1=0.0525. The compound has the [Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H+ cations play a role of charge-balance.",

keywords = "Benzimidazole, Compound, Polyoxometalate",

author = "Zhang, {Zhong Qiang} and Huang, {Ru Dan} and Xu, {Yan Qing} and Jiao, {Zhi Wei} and Hu, {Chang Wen}",

year = "2008",

month = dec,

language = "English",

volume = "28",

pages = "1109--1112",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "12",

}

TY - JOUR

T1 - A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O

AU - Zhang, Zhong Qiang

AU - Huang, Ru Dan

AU - Xu, Yan Qing

AU - Jiao, Zhi Wei

AU - Hu, Chang Wen

PY - 2008/12

Y1 - 2008/12

N2 - A new compound, H2[Hbim]2 [(bim)2Mo8O26]·H2O (bim=benzimidazole), was synthesized by benzimidazole, MoO3, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm3, Z=2, R1=0.0525. The compound has the [Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H+ cations play a role of charge-balance.

AB - A new compound, H2[Hbim]2 [(bim)2Mo8O26]·H2O (bim=benzimidazole), was synthesized by benzimidazole, MoO3, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm3, Z=2, R1=0.0525. The compound has the [Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H+ cations play a role of charge-balance.

KW - Benzimidazole

KW - Compound

KW - Polyoxometalate

UR - http://www.scopus.com/inward/record.url?scp=58249138846&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:58249138846

SN - 1001-0645

VL - 28

SP - 1109

EP - 1112

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 12

ER -

A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O

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A new method of synthesis for the compound H₂[Hbim]₂ [(Bim)₂Mo₈O₂₆]·H₂O