TY - JOUR
T1 - A new inorganic-organic hybrid with zinc phosphate layers pillared by the 4,4′-bipyridine units
AU - Lin, Zhi En
AU - Zhang, Jie
AU - Zheng, Shou Tian
AU - Yang, Guo Yu
PY - 2005
Y1 - 2005
N2 - A new inorganic-organic hybrid zinc phosphate with the formula Zn 2(4,4′-bipy)(HPO4)2 (4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, ICP analysis, elemental analysis, SEM, powder X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the monoclinic system, space group P21/c (No. 14), a = 10.4479(7), b = 8.1694(5), c = 8.9643(5) Å, β = 97.907(2), V = 757.86(8) Å3, Z = 2. The structure consists of ZnO3N and HPO4 tetrahedra by corner-sharing to generate neutral 4.82-net sheets, which are pillared through 4,4′-bipy ligands to form a 3-D hybrid framework.
AB - A new inorganic-organic hybrid zinc phosphate with the formula Zn 2(4,4′-bipy)(HPO4)2 (4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, ICP analysis, elemental analysis, SEM, powder X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the monoclinic system, space group P21/c (No. 14), a = 10.4479(7), b = 8.1694(5), c = 8.9643(5) Å, β = 97.907(2), V = 757.86(8) Å3, Z = 2. The structure consists of ZnO3N and HPO4 tetrahedra by corner-sharing to generate neutral 4.82-net sheets, which are pillared through 4,4′-bipy ligands to form a 3-D hybrid framework.
KW - Crystal elucidation
KW - Hybrid
KW - Hydrothermal synthesis
KW - Phosphate
KW - Zinc
UR - http://www.scopus.com/inward/record.url?scp=12344262098&partnerID=8YFLogxK
U2 - 10.1002/zaac.200400379
DO - 10.1002/zaac.200400379
M3 - Article
AN - SCOPUS:12344262098
SN - 0044-2313
VL - 631
SP - 155
EP - 159
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 1
ER -