A New Hepta-Nuclear Ti-Oxo-Cluster-Substituted Tungstoantimonate and Its Catalytic Oxidation of Thioethers

Hai Lou Li; Chen Lian; Da Peng Yin; Zhi Yu Jia; Guo Yu Yang

doi:10.1021/acs.cgd.8b01474

A New Hepta-Nuclear Ti-Oxo-Cluster-Substituted Tungstoantimonate and Its Catalytic Oxidation of Thioethers

Hai Lou Li, Chen Lian, Da Peng Yin, Zhi Yu Jia, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

30 引用（Scopus）

摘要

A neoteric hepta-nuclear Ti-oxo-cluster-substituted tetrameric tungstoantimonate [H ₂ N(CH ₃ ) ₂ ] ₂₂ Na ₁₈ {Ti ₇ O ₆ (SbW ₉ O ₃₃ ) ₄ } ₂ ·124H ₂ O (1) has hydrothermally been synthesized and tested by single-crystal/powder X-ray diffraction, IR spectra, and thermal analysis. The glamorous feature of this tetrameric polyoxoanion is an uncommon hepta-nuclear Ti-oxo-cluster octahedron [Ti ₇ O ₆ ] ¹⁶⁺ enclosed in four [B-α-SbW ₉ O ₃₃ ] ^9- building units. As a heterogeneous catalyst, the investigation on catalytic oxidation with H ₂ O ₂ for multiple thioethers indicated that 1 possesses high conversion and remarkable selectivity. Additionally, 1 exhibits good stability and excellent recyclability.

源语言	英语
页（从-至）	376-380
页数	5
期刊	Crystal Growth and Design
卷	19
期	1
DOI	https://doi.org/10.1021/acs.cgd.8b01474
出版状态	已出版 - 2 1月 2019

访问文件

10.1021/acs.cgd.8b01474

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{78b7e09ddfc3434a90aaae0e321bf777,

title = "A New Hepta-Nuclear Ti-Oxo-Cluster-Substituted Tungstoantimonate and Its Catalytic Oxidation of Thioethers",

abstract = " A neoteric hepta-nuclear Ti-oxo-cluster-substituted tetrameric tungstoantimonate [H 2 N(CH 3 ) 2 ] 22 Na 18 {Ti 7 O 6 (SbW 9 O 33 ) 4 } 2 ·124H 2 O (1) has hydrothermally been synthesized and tested by single-crystal/powder X-ray diffraction, IR spectra, and thermal analysis. The glamorous feature of this tetrameric polyoxoanion is an uncommon hepta-nuclear Ti-oxo-cluster octahedron [Ti 7 O 6 ] 16+ enclosed in four [B-α-SbW 9 O 33 ] 9- building units. As a heterogeneous catalyst, the investigation on catalytic oxidation with H 2 O 2 for multiple thioethers indicated that 1 possesses high conversion and remarkable selectivity. Additionally, 1 exhibits good stability and excellent recyclability.",

author = "Li, {Hai Lou} and Chen Lian and Yin, {Da Peng} and Jia, {Zhi Yu} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2019",

month = jan,

day = "2",

doi = "10.1021/acs.cgd.8b01474",

language = "English",

volume = "19",

pages = "376--380",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - A New Hepta-Nuclear Ti-Oxo-Cluster-Substituted Tungstoantimonate and Its Catalytic Oxidation of Thioethers

AU - Li, Hai Lou

AU - Lian, Chen

AU - Yin, Da Peng

AU - Jia, Zhi Yu

AU - Yang, Guo Yu

PY - 2019/1/2

Y1 - 2019/1/2

N2 - A neoteric hepta-nuclear Ti-oxo-cluster-substituted tetrameric tungstoantimonate [H 2 N(CH 3 ) 2 ] 22 Na 18 {Ti 7 O 6 (SbW 9 O 33 ) 4 } 2 ·124H 2 O (1) has hydrothermally been synthesized and tested by single-crystal/powder X-ray diffraction, IR spectra, and thermal analysis. The glamorous feature of this tetrameric polyoxoanion is an uncommon hepta-nuclear Ti-oxo-cluster octahedron [Ti 7 O 6 ] 16+ enclosed in four [B-α-SbW 9 O 33 ] 9- building units. As a heterogeneous catalyst, the investigation on catalytic oxidation with H 2 O 2 for multiple thioethers indicated that 1 possesses high conversion and remarkable selectivity. Additionally, 1 exhibits good stability and excellent recyclability.

AB - A neoteric hepta-nuclear Ti-oxo-cluster-substituted tetrameric tungstoantimonate [H 2 N(CH 3 ) 2 ] 22 Na 18 {Ti 7 O 6 (SbW 9 O 33 ) 4 } 2 ·124H 2 O (1) has hydrothermally been synthesized and tested by single-crystal/powder X-ray diffraction, IR spectra, and thermal analysis. The glamorous feature of this tetrameric polyoxoanion is an uncommon hepta-nuclear Ti-oxo-cluster octahedron [Ti 7 O 6 ] 16+ enclosed in four [B-α-SbW 9 O 33 ] 9- building units. As a heterogeneous catalyst, the investigation on catalytic oxidation with H 2 O 2 for multiple thioethers indicated that 1 possesses high conversion and remarkable selectivity. Additionally, 1 exhibits good stability and excellent recyclability.

UR - http://www.scopus.com/inward/record.url?scp=85059509121&partnerID=8YFLogxK

U2 - 10.1021/acs.cgd.8b01474

DO - 10.1021/acs.cgd.8b01474

M3 - Article

AN - SCOPUS:85059509121

SN - 1528-7483

VL - 19

SP - 376

EP - 380

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 1

ER -

A New Hepta-Nuclear Ti-Oxo-Cluster-Substituted Tungstoantimonate and Its Catalytic Oxidation of Thioethers

摘要

访问文件

其它文件与链接

指纹

引用此