A New 2-D network containing {As4V16O 42(H2O)} cluster units

Jian Zhou; Shou Tian Zheng; Wei Hui Fang; Guo Yu Yang

doi:10.1002/ejic.200900596

A New 2-D network containing {As₄V₁₆O ₄₂(H₂O)} cluster units

Jian Zhou, Shou Tian Zheng, Wei Hui Fang, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

34 引用（Scopus）

摘要

A new polyoxometalate [Cd(dien)]₂[Cd(dien)(H₂O)] ₂[As₄V₁₆O₄₂(H₂O)] ·2H₂O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As₄V₁₆O ₄₂(H₂O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between V^IV cations in 1.

源语言	英语
页（从-至）	5075-5078
页数	4
期刊	European Journal of Inorganic Chemistry
期	34
DOI	https://doi.org/10.1002/ejic.200900596
出版状态	已出版 - 2009
已对外发布	是

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Zhou, J., Zheng, S. T., Fang, W. H., & Yang, G. Y. (2009). A New 2-D network containing {As₄V₁₆O ₄₂(H₂O)} cluster units. European Journal of Inorganic Chemistry, (34), 5075-5078. https://doi.org/10.1002/ejic.200900596

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title = "A New 2-D network containing {As4V16O 42(H2O)} cluster units",

abstract = "A new polyoxometalate [Cd(dien)]2[Cd(dien)(H2O)] 2[As4V16O42(H2O)] ·2H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As4V16O 42(H2O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between VIV cations in 1.",

keywords = "Arsenic, Cluster compounds, Hydrothermal synthesis, Polyoxometalates, Vanadium",

author = "Jian Zhou and Zheng, {Shou Tian} and Fang, {Wei Hui} and Yang, {Guo Yu}",

year = "2009",

doi = "10.1002/ejic.200900596",

language = "English",

pages = "5075--5078",

journal = "European Journal of Inorganic Chemistry",

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T1 - A New 2-D network containing {As4V16O 42(H2O)} cluster units

AU - Zhou, Jian

AU - Zheng, Shou Tian

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - A new polyoxometalate [Cd(dien)]2[Cd(dien)(H2O)] 2[As4V16O42(H2O)] ·2H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As4V16O 42(H2O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between VIV cations in 1.

AB - A new polyoxometalate [Cd(dien)]2[Cd(dien)(H2O)] 2[As4V16O42(H2O)] ·2H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As4V16O 42(H2O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between VIV cations in 1.

KW - Arsenic

KW - Cluster compounds

KW - Hydrothermal synthesis

KW - Polyoxometalates

KW - Vanadium

UR - http://www.scopus.com/inward/record.url?scp=72949094017&partnerID=8YFLogxK

U2 - 10.1002/ejic.200900596

DO - 10.1002/ejic.200900596

M3 - Article

AN - SCOPUS:72949094017

SN - 1434-1948

SP - 5075

EP - 5078

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 34

ER -

A New 2-D network containing {As4V16O 42(H2O)} cluster units

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A New 2-D network containing {As₄V₁₆O ₄₂(H₂O)} cluster units