A Mild Multi-Component Reaction for the Synthesis of 4,5-Disubstituted 1 H -1,2,3-Triazoles from Phosphonium Salts, Aldehydes, and Sodium Azide

Guang Long Wu*, Qin Pei Wu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

18 引用 (Scopus)

摘要

A mild and metal-free multi-component reaction to synthesize 4,5-disubstituted 1 H -1,2,3-triazoles from phosphonium salts, aldehydes, and sodium azide is described. The process undergoes an organocatalyzed coupling of formyl group with phosphonium to form a key intermediate, olefinic phosphonium salt, which is followed by the [3+2] cycloaddition of the azide to the activated alkene. A series of representative 4,5-disubstituted 1 H -1,2,3-triazoles were prepared.

源语言英语
页(从-至)2768-2774
页数7
期刊Synthesis
50
14
DOI
出版状态已出版 - 17 7月 2018

指纹

探究 'A Mild Multi-Component Reaction for the Synthesis of 4,5-Disubstituted 1 H -1,2,3-Triazoles from Phosphonium Salts, Aldehydes, and Sodium Azide' 的科研主题。它们共同构成独一无二的指纹。

引用此