A metallocene-complexed dibismuthene: Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes 2)

Yuzhong Wang; Brandon Quillian; Xiao Juan Yang; Pingrong Wei; Zhongfang Chen; Chaitanya S. Wannere; Paul V.R. Schleyer; Gregory H. Robinson

doi:10.1021/ja051704h

A metallocene-complexed dibismuthene: Cp₂Zr(BiR)₂ (Cp = C₅H₅; R = C₆H₃-2,6-Mes ₂)

Yuzhong Wang, Brandon Quillian, Xiao Juan Yang, Pingrong Wei, Zhongfang Chen, Chaitanya S. Wannere, Paul V.R. Schleyer^*, Gregory H. Robinson

^*此作品的通讯作者

University of Georgia

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

The zirconocene-complexed dibismuthene, Cp₂Zr(BiR)₂ (Cp = C₅H₅; R = C₆H₃-2,6-Mes₂), was prepared by the reaction of sodium metal with Cp₂ZrCl₂ and RBiCl₂. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi-Zr bonds and the only example of a ZrBi₂ ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center.

源语言	英语
页（从-至）	7672-7673
页数	2
期刊	Journal of the American Chemical Society
卷	127
期	21
DOI	https://doi.org/10.1021/ja051704h
出版状态	已出版 - 1 6月 2005
已对外发布	是

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10.1021/ja051704h

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Wang, Y., Quillian, B., Yang, X. J., Wei, P., Chen, Z., Wannere, C. S., Schleyer, P. V. R., & Robinson, G. H. (2005). A metallocene-complexed dibismuthene: Cp₂Zr(BiR)₂ (Cp = C₅H₅; R = C₆H₃-2,6-Mes ₂). Journal of the American Chemical Society, 127(21), 7672-7673. https://doi.org/10.1021/ja051704h

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abstract = "The zirconocene-complexed dibismuthene, Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2), was prepared by the reaction of sodium metal with Cp2ZrCl2 and RBiCl2. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi-Zr bonds and the only example of a ZrBi2 ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center.",

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year = "2005",

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AU - Wang, Yuzhong

AU - Quillian, Brandon

AU - Yang, Xiao Juan

AU - Wei, Pingrong

AU - Chen, Zhongfang

AU - Wannere, Chaitanya S.

AU - Schleyer, Paul V.R.

AU - Robinson, Gregory H.

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N2 - The zirconocene-complexed dibismuthene, Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2), was prepared by the reaction of sodium metal with Cp2ZrCl2 and RBiCl2. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi-Zr bonds and the only example of a ZrBi2 ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center.

AB - The zirconocene-complexed dibismuthene, Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes2), was prepared by the reaction of sodium metal with Cp2ZrCl2 and RBiCl2. The air- and moisture-sensitive dark reddish/brown compound is the first organometallic compound containing Bi-Zr bonds and the only example of a ZrBi2 ring. Moreover, our computations on associated model systems offer insight into the nature of the interaction of the heaviest dipnictene with a metallocene center.

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A metallocene-complexed dibismuthene: Cp2Zr(BiR)2 (Cp = C5H5; R = C6H3-2,6-Mes 2)

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A metallocene-complexed dibismuthene: Cp₂Zr(BiR)₂ (Cp = C₅H₅; R = C₆H₃-2,6-Mes ₂)