A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

Xiao Peng Sun; Zheng Tang; Zi Shuo Yao; Jun Tao

doi:10.1039/c9cc09063k

A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

Xiao Peng Sun, Zheng Tang, Zi Shuo Yao^*, Jun Tao

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

15 引用（Scopus）

摘要

An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

源语言	英语
页（从-至）	133-136
页数	4
期刊	Chemical Communications
卷	56
期	1
DOI	https://doi.org/10.1039/c9cc09063k
出版状态	已出版 - 2019

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Sun, X. P., Tang, Z., Yao, Z. S., & Tao, J. (2019). A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors. Chemical Communications, 56(1), 133-136. https://doi.org/10.1039/c9cc09063k

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title = "A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors",

abstract = "An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.",

author = "Sun, {Xiao Peng} and Zheng Tang and Yao, {Zi Shuo} and Jun Tao",

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AU - Sun, Xiao Peng

AU - Tang, Zheng

AU - Yao, Zi Shuo

AU - Tao, Jun

PY - 2019

Y1 - 2019

N2 - An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

AB - An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

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A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

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