A germanate framework containing 24-ring channels, Ni-Ge bonds, and chiral [Ni@Ge14O24(OH)3] cluster motifs transferred from chiral metal complexes

Zhi En Lin*, Jie Zhang, Jing Tai Zhao, Shou Tian Zheng, Chun Yang Pan, Guo Ming Wang, Guo Yu Yang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

122 引用 (Scopus)

摘要

(Figure Presented) Microporous: Chiral metal complexes as templates under solvothermal conditions resulted in two novel germanates Ni@Ge 14O24(OH)3·2 Ni(L)3 (L = ethylene-diamine, 1,2-diaminopropane). The chiral Ni@Ge14O 24(OH)3 cluster motifs have an unprecedented trigonal-bipyramidal Ni@Ge5 core with Ni-Ge bonds and are linked to each other to form a 3D germanate framework containing 24-ring channels (see picture).

源语言英语
页(从-至)6881-6884
页数4
期刊Angewandte Chemie - International Edition
44
42
DOI
出版状态已出版 - 28 10月 2005
已对外发布

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