A flexible 1,8-naphthyridyl derivative and its Zn(II) complexes: Synthesis, structures, spectroscopic properties and recognition of Cd(II)

Hui Miao Zhang; Wen Fu Fu; Xin Gan; Yan Qing Xu; Jun Wang; Quan Qing Xu; Shao Ming Chi

doi:10.1039/b809701a

A flexible 1,8-naphthyridyl derivative and its Zn(II) complexes: Synthesis, structures, spectroscopic properties and recognition of Cd(II)

Hui Miao Zhang, Wen Fu Fu^*, Xin Gan, Yan Qing Xu, Jun Wang, Quan Qing Xu, Shao Ming Chi

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化学与化工学院

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摘要

A flexible ligand bis(7-methyl-1,8-naphthyridine-2-ylamino)methane (L), having κ⁴-chelating and κ²-bridging modes, and its intriguing structural complexes of Zn(II) with μ-OH, κ¹-OAc, μ-κ¹-OAc and μ- κ²-OAc ligands, [Zn₂(L)₂(OH)](ClO ₄)₃ (1), [Zn₄(L)₂(OAc) ₆(OH)₂]·CH₂Cl₂ (2·CH₂Cl₂) and [Zn₅(L) ₂(OAc)₁₀]_n·4nH₂O (3·4H₂O) were synthesized and their structures were determined by X-ray crystallography. These compounds exhibited intense blue fluorescent emissions with a λ_max in the range of 380-410 nm in CH ₂Cl₂, CH₃CN and CH₃OH solutions, and solid-state emissions centered at 416, 463, 490 and 451 nm were observed for the compounds L, 1, 2 and 3 at room temperature, respectively. The investigated fluorescence properties of L associated with various metal ions showed that the fluorescence enhancement of L with Cd(II) was more sensitive than with other interfering cations.

源语言	英语
页（从-至）	6817-6824
页数	8
期刊	Dalton Transactions
期	47
DOI	https://doi.org/10.1039/b809701a
出版状态	已出版 - 2008

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@article{ad82b9af651447e6a447aced1187b7bd,

title = "A flexible 1,8-naphthyridyl derivative and its Zn(II) complexes: Synthesis, structures, spectroscopic properties and recognition of Cd(II)",

abstract = "A flexible ligand bis(7-methyl-1,8-naphthyridine-2-ylamino)methane (L), having κ4-chelating and κ2-bridging modes, and its intriguing structural complexes of Zn(II) with μ-OH, κ1-OAc, μ-κ1-OAc and μ- κ2-OAc ligands, [Zn2(L)2(OH)](ClO 4)3 (1), [Zn4(L)2(OAc) 6(OH)2]·CH2Cl2 (2·CH2Cl2) and [Zn5(L) 2(OAc)10]n·4nH2O (3·4H2O) were synthesized and their structures were determined by X-ray crystallography. These compounds exhibited intense blue fluorescent emissions with a λmax in the range of 380-410 nm in CH 2Cl2, CH3CN and CH3OH solutions, and solid-state emissions centered at 416, 463, 490 and 451 nm were observed for the compounds L, 1, 2 and 3 at room temperature, respectively. The investigated fluorescence properties of L associated with various metal ions showed that the fluorescence enhancement of L with Cd(II) was more sensitive than with other interfering cations.",

author = "Zhang, {Hui Miao} and Fu, {Wen Fu} and Xin Gan and Xu, {Yan Qing} and Jun Wang and Xu, {Quan Qing} and Chi, {Shao Ming}",

year = "2008",

doi = "10.1039/b809701a",

language = "English",

pages = "6817--6824",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "47",

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T1 - A flexible 1,8-naphthyridyl derivative and its Zn(II) complexes

T2 - Synthesis, structures, spectroscopic properties and recognition of Cd(II)

AU - Zhang, Hui Miao

AU - Fu, Wen Fu

AU - Gan, Xin

AU - Xu, Yan Qing

AU - Wang, Jun

AU - Xu, Quan Qing

AU - Chi, Shao Ming

PY - 2008

Y1 - 2008

N2 - A flexible ligand bis(7-methyl-1,8-naphthyridine-2-ylamino)methane (L), having κ4-chelating and κ2-bridging modes, and its intriguing structural complexes of Zn(II) with μ-OH, κ1-OAc, μ-κ1-OAc and μ- κ2-OAc ligands, [Zn2(L)2(OH)](ClO 4)3 (1), [Zn4(L)2(OAc) 6(OH)2]·CH2Cl2 (2·CH2Cl2) and [Zn5(L) 2(OAc)10]n·4nH2O (3·4H2O) were synthesized and their structures were determined by X-ray crystallography. These compounds exhibited intense blue fluorescent emissions with a λmax in the range of 380-410 nm in CH 2Cl2, CH3CN and CH3OH solutions, and solid-state emissions centered at 416, 463, 490 and 451 nm were observed for the compounds L, 1, 2 and 3 at room temperature, respectively. The investigated fluorescence properties of L associated with various metal ions showed that the fluorescence enhancement of L with Cd(II) was more sensitive than with other interfering cations.

AB - A flexible ligand bis(7-methyl-1,8-naphthyridine-2-ylamino)methane (L), having κ4-chelating and κ2-bridging modes, and its intriguing structural complexes of Zn(II) with μ-OH, κ1-OAc, μ-κ1-OAc and μ- κ2-OAc ligands, [Zn2(L)2(OH)](ClO 4)3 (1), [Zn4(L)2(OAc) 6(OH)2]·CH2Cl2 (2·CH2Cl2) and [Zn5(L) 2(OAc)10]n·4nH2O (3·4H2O) were synthesized and their structures were determined by X-ray crystallography. These compounds exhibited intense blue fluorescent emissions with a λmax in the range of 380-410 nm in CH 2Cl2, CH3CN and CH3OH solutions, and solid-state emissions centered at 416, 463, 490 and 451 nm were observed for the compounds L, 1, 2 and 3 at room temperature, respectively. The investigated fluorescence properties of L associated with various metal ions showed that the fluorescence enhancement of L with Cd(II) was more sensitive than with other interfering cations.

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U2 - 10.1039/b809701a

DO - 10.1039/b809701a

M3 - Article

AN - SCOPUS:56849128816

SN - 1477-9226

SP - 6817

EP - 6824

JO - Dalton Transactions

JF - Dalton Transactions

IS - 47

ER -

A flexible 1,8-naphthyridyl derivative and its Zn(II) complexes: Synthesis, structures, spectroscopic properties and recognition of Cd(II)

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