A C-C bonded 5,6-fused bicyclic energetic molecule: Exploring an advanced energetic compound with improved performance

Yongxing Tang; Chunlin He; Gregory H. Imler; Damon A. Parrish; Jean'Ne M. Shreeve

doi:10.1039/c8cc05987j

A C-C bonded 5,6-fused bicyclic energetic molecule: Exploring an advanced energetic compound with improved performance

Yongxing Tang, Chunlin He, Gregory H. Imler, Damon A. Parrish, Jean'Ne M. Shreeve^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

64 引用（Scopus）

摘要

A C-C bonded amino-nitro pyrazole (7) and its ring-expansion product (9) have been synthesized and characterized. The synthetic route to 9 proceeds in several steps from the commercial substrate diethyl oxalate and acetone. The process was found to be straightforward, practical and easily scalable. Both of these structures were confirmed by single crystal X-ray diffraction. Compound 9 with a high density (1.85 g cm^-3) at room temperature, excellent thermal stability (T_d: 315 °C), good detonation performance and low sensitivity to impact and friction has potential as a high-temperature energetic material.

源语言	英语
页（从-至）	10566-10569
页数	4
期刊	Chemical Communications
卷	54
期	75
DOI	https://doi.org/10.1039/c8cc05987j
出版状态	已出版 - 2018
已对外发布	是

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abstract = "A C-C bonded amino-nitro pyrazole (7) and its ring-expansion product (9) have been synthesized and characterized. The synthetic route to 9 proceeds in several steps from the commercial substrate diethyl oxalate and acetone. The process was found to be straightforward, practical and easily scalable. Both of these structures were confirmed by single crystal X-ray diffraction. Compound 9 with a high density (1.85 g cm-3) at room temperature, excellent thermal stability (Td: 315 °C), good detonation performance and low sensitivity to impact and friction has potential as a high-temperature energetic material.",

author = "Yongxing Tang and Chunlin He and Imler, {Gregory H.} and Parrish, {Damon A.} and Shreeve, {Jean'Ne M.}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc05987j",

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T1 - A C-C bonded 5,6-fused bicyclic energetic molecule

T2 - Exploring an advanced energetic compound with improved performance

AU - Tang, Yongxing

AU - He, Chunlin

AU - Imler, Gregory H.

AU - Parrish, Damon A.

AU - Shreeve, Jean'Ne M.

PY - 2018

Y1 - 2018

N2 - A C-C bonded amino-nitro pyrazole (7) and its ring-expansion product (9) have been synthesized and characterized. The synthetic route to 9 proceeds in several steps from the commercial substrate diethyl oxalate and acetone. The process was found to be straightforward, practical and easily scalable. Both of these structures were confirmed by single crystal X-ray diffraction. Compound 9 with a high density (1.85 g cm-3) at room temperature, excellent thermal stability (Td: 315 °C), good detonation performance and low sensitivity to impact and friction has potential as a high-temperature energetic material.

AB - A C-C bonded amino-nitro pyrazole (7) and its ring-expansion product (9) have been synthesized and characterized. The synthetic route to 9 proceeds in several steps from the commercial substrate diethyl oxalate and acetone. The process was found to be straightforward, practical and easily scalable. Both of these structures were confirmed by single crystal X-ray diffraction. Compound 9 with a high density (1.85 g cm-3) at room temperature, excellent thermal stability (Td: 315 °C), good detonation performance and low sensitivity to impact and friction has potential as a high-temperature energetic material.

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EP - 10569

JO - Chemical Communications

JF - Chemical Communications

IS - 75

ER -

A C-C bonded 5,6-fused bicyclic energetic molecule: Exploring an advanced energetic compound with improved performance

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