A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)

Man Bo Zhang, Yong Mei Chen, Shou Tian Zheng, Guo Yu Yang*

*此作品的通讯作者

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摘要

A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.

源语言英语
页（从-至）1423-1428
页数6
期刊European Journal of Inorganic Chemistry
期7
DOI
出版状态已出版 - 3 4月 2006
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Zhang, M. B., Chen, Y. M., Zheng, S. T., & Yang, G. Y. (2006). A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate). European Journal of Inorganic Chemistry, (7), 1423-1428. https://doi.org/10.1002/ejic.200500883