摘要
A novel homochiral 3D copper(II)-organic framework has been synthesized under solvothermal reaction. Single-crystal X-ray diffraction reveals it features a fascinating 3D cationic framework with SO42- and water molecule occupying its central of channel. Moreover, the unique triple-stranded helices in the structure based on tetranuclear CopperII Cluster Node are further linked by the UCA ligand (UCA=Urocanic acid) and give rise to the resultant homochiral network, which can be described as a rarely observed 4966 topology.
源语言 | 英语 |
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页(从-至) | 852-854 |
页数 | 3 |
期刊 | Inorganic Chemistry Communications |
卷 | 13 |
期 | 7 |
DOI | |
出版状态 | 已出版 - 7月 2010 |
指纹
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Xu, Y., Xi, J., Wei, W., Chi, Y., & Hu, C. (2010). A 3D homochiral framework with rare 49•66 structural topology constructed by unique triple-stranded helices. Inorganic Chemistry Communications, 13(7), 852-854. https://doi.org/10.1016/j.inoche.2010.04.011