A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Man Bo Zhang; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/anie.200461424

A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Man Bo Zhang, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

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344 引用（Scopus）

摘要

Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln₁₄, (μ₆-O)(μ₃-OH)₂₀(H₂O) ₈]²⁰⁺ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

源语言	英语
页（从-至）	1385-1388
页数	4
期刊	Angewandte Chemie - International Edition
卷	44
期	9
DOI	https://doi.org/10.1002/anie.200461424
出版状态	已出版 - 18 2月 2005
已对外发布	是

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title = "A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands",

abstract = "Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.",

keywords = "Bridging ligands, Cluster compounds, Copper, Hydrothermal synthesis, Lanthanides",

author = "Zhang, {Man Bo} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

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T1 - A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

AU - Zhang, Man Bo

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005/2/18

Y1 - 2005/2/18

N2 - Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

AB - Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

KW - Bridging ligands

KW - Cluster compounds

KW - Copper

KW - Hydrothermal synthesis

KW - Lanthanides

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

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