TY - JOUR
T1 - 4-Chloro-3,5-dinitropyrazole
T2 - A precursor for promising insensitive energetic compounds
AU - He, Chunlin
AU - Zhang, Jiaheng
AU - Parrish, Damon A.
AU - Shreeve, Jean'Ne M.
PY - 2013/2/28
Y1 - 2013/2/28
N2 - A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, 1H, and 13C NMR (some cases 15N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.
AB - A series of 3,5-dinitropyrazole derivatives was prepared from 4-chloro-3,5-dinitropyrazole in good yields and characterized by IR, 1H, and 13C NMR (some cases 15N NMR) spectroscopy, elemental analysis, and DSC. The structures of 7 and 13 were confirmed by single crystal X-ray diffraction. The impact sensitivity was determined using a standard BAM method, and detonation properties were obtained using experimental densities and calculated heats of formation.
UR - http://www.scopus.com/inward/record.url?scp=84876566247&partnerID=8YFLogxK
U2 - 10.1039/c2ta01359b
DO - 10.1039/c2ta01359b
M3 - Article
AN - SCOPUS:84876566247
SN - 2050-7488
VL - 1
SP - 2863
EP - 2868
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
IS - 8
ER -
