2,2′-Bisdinitromethyl-5,5′-bistetrazole: A High-Performance, Multi-Nitro Energetic Material with Excellent Oxygen Balance

Yiling Yang; Wenjin Zhang; Siping Pang; He Huang; Chenghui Sun

doi:10.1021/acs.joc.4c01338

2,2′-Bisdinitromethyl-5,5′-bistetrazole: A High-Performance, Multi-Nitro Energetic Material with Excellent Oxygen Balance

Yiling Yang, Wenjin Zhang, Siping Pang, He Huang^*, Chenghui Sun^*

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Bistetrazoles are highly sought after for developing innovative high-energy density materials. The 1,1′-substituted bistetrazoles, exemplified by TKX-50, have outstanding performance. However, the research of high-perfomance 2,2′-substituted bistetrazoles remains limited. In this work, dinitromethyl groups were introduced into bistetrazole structures as 2,2′-substituted bistetrazoles (BDBTZ), which was extensively characterized through NMR, thermal analysis, and single crystal X-ray diffraction, exhibiting excellent oxygen balance, moderate sensitivity, acceptable thermal stability, high crystal density, and excellent detonation performance.

源语言	英语
页（从-至）	12790-12794
页数	5
期刊	Journal of Organic Chemistry
卷	89
期	17
DOI	https://doi.org/10.1021/acs.joc.4c01338
出版状态	已出版 - 6 9月 2024

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10.1021/acs.joc.4c01338

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Yang, Y., Zhang, W., Pang, S., Huang, H., & Sun, C. (2024). 2,2′-Bisdinitromethyl-5,5′-bistetrazole: A High-Performance, Multi-Nitro Energetic Material with Excellent Oxygen Balance. Journal of Organic Chemistry, 89(17), 12790-12794. https://doi.org/10.1021/acs.joc.4c01338

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abstract = "Bistetrazoles are highly sought after for developing innovative high-energy density materials. The 1,1′-substituted bistetrazoles, exemplified by TKX-50, have outstanding performance. However, the research of high-perfomance 2,2′-substituted bistetrazoles remains limited. In this work, dinitromethyl groups were introduced into bistetrazole structures as 2,2′-substituted bistetrazoles (BDBTZ), which was extensively characterized through NMR, thermal analysis, and single crystal X-ray diffraction, exhibiting excellent oxygen balance, moderate sensitivity, acceptable thermal stability, high crystal density, and excellent detonation performance.",

author = "Yiling Yang and Wenjin Zhang and Siping Pang and He Huang and Chenghui Sun",

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AU - Yang, Yiling

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AU - Pang, Siping

AU - Huang, He

AU - Sun, Chenghui

PY - 2024/9/6

Y1 - 2024/9/6

N2 - Bistetrazoles are highly sought after for developing innovative high-energy density materials. The 1,1′-substituted bistetrazoles, exemplified by TKX-50, have outstanding performance. However, the research of high-perfomance 2,2′-substituted bistetrazoles remains limited. In this work, dinitromethyl groups were introduced into bistetrazole structures as 2,2′-substituted bistetrazoles (BDBTZ), which was extensively characterized through NMR, thermal analysis, and single crystal X-ray diffraction, exhibiting excellent oxygen balance, moderate sensitivity, acceptable thermal stability, high crystal density, and excellent detonation performance.

AB - Bistetrazoles are highly sought after for developing innovative high-energy density materials. The 1,1′-substituted bistetrazoles, exemplified by TKX-50, have outstanding performance. However, the research of high-perfomance 2,2′-substituted bistetrazoles remains limited. In this work, dinitromethyl groups were introduced into bistetrazole structures as 2,2′-substituted bistetrazoles (BDBTZ), which was extensively characterized through NMR, thermal analysis, and single crystal X-ray diffraction, exhibiting excellent oxygen balance, moderate sensitivity, acceptable thermal stability, high crystal density, and excellent detonation performance.

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2,2′-Bisdinitromethyl-5,5′-bistetrazole: A High-Performance, Multi-Nitro Energetic Material with Excellent Oxygen Balance

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