赵娣,硕博士生导师。以国家双碳大目标为背景,通过利用电/光等新能源方式实现氢能的制取、利用和实现温室气体CO2有价值化学品转化。具体聚焦在纳米、团簇、单原子催化剂的表界面调控合成及在涉及H2、O2、CO2小分子反应的燃料电池、电解水、CO2电还原等新能源方向的基础应用研究。相关研究成果以第一和通讯作者在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commun.、Energy Environ. Sci.、Chem. Soc. Rev.、ACS Nano等国际学术期刊上发表论文20余篇,部分论文被邀请做杂志封面和被C&EN特别报道,其中ESI高被引论文3篇。申请国际专利两项,授权一项。获第二届博士后创新人才支持计划。作为课题负责人承担中国博士后科学基金面上项目,国家自然科学基金青年基金项目、企业横向课题等。
1.纳米、团簇、单原子催化剂合成及催化性能研究
2.电解水、CO2电还原、氧还原、氢氧化等新能源相关电催化剂的开发及应用
2016.09-2017.06 德雷塞尔大学,材料科学与工程学院,联合培养博士
2011.09-2017.07 北京理工大学,化学专业,理学博士
2017.07-2020.07 清华大学,化学系,博新博士后
2020.07-至今 北京理工大学化学与化工学院,预聘副教授
1.Mengyun Hou,1,+ Lirong Zheng,2,+ Di Zhao,1,* Xin Tan,3 Wuyi Feng,1 Jiantao Fu, 1 Tianxin Wei,1 Minhua Cao,*,1 Jiatao Zhang,*,1 Chen Chen,*,3 Microenvironment Reconstitution of Highly Active Ni Single Atoms on Oxygen-Incorporated Mo2C for Water Splitting, Nat. Commun., 2024, 15,1342.
2.Pan Zhu,+ Wuyi Feng,+ Di Zhao,* Pengyu Song, Mengwei Li, Xin Tan, Ting Liu, Shoujie Liu,* Wei Zhu, Zhongbin Zhuang, Jiatao Zhang* and Chen Chen*, p-Block Bismuth Nanoclusters Sites Activated by Atomically Dispersed Bismuth for Tandem Boosting Electrocatalytic Hydrogen Peroxide Production, Angew. Chem. Int. Ed., 2023, 135, e202304488. (Hot paper)
3.Di Zhao,#,* Ke Yu,# Pengyu Song,# Wuyi Feng, Botao Hu, Weng-Chon (Max) Cheong, Zewen Zhuang, Shoujie Liu,* Kaian Sun, Jiatao Zhang* and Chen Chen,* Atomic-level engineering Fe1N2O2 interfacial structure derived from oxygen-abundant metal–organic frameworks to promote electrochemical CO2 reduction, Energy Environ. Sci., 2022, 15, 3795-3804.
4.Di Zhao#, Zheng Chen#, Wenjuan Yang#, Shoujie Liu,Xun Zhang, Yi Yu, Weng-Chon Cheong, Lirong Zheng, Fuqiang Ren, Guobing Ying, Xing Cao, Dingsheng Wang, Qing Peng, Guoxiu Wang, and Chen Chen*, MXene (Ti3C2) vacancy-confined single-atom catalyst for efficient functionalization of CO2, J. Am. Chem. Soc., 2019, 141, 4086-4093. (Cover paper; Highly cited paper; Highlighted by Chemical & Engineering News)
5.Di Zhao#, Kaian Sun#, Weng-Chon Cheong, Lirong Zheng, Chao Zhang, Shoujie Liu, Xing Cao, Konglin Wu, Yuan Pan, Zewen Zhuang, Botao Hu, Dingsheng Wang, Qing Peng, Chen Chen*, and Yadong Li, Synergistically Interactive Pyridinic-N-MoP Sites: Identified Active Centers for Enhanced Hydrogen Evolution in Alkaline Solution, Angew. Chem. Int. Ed., 2020, 59, 8982-8990.
6.Di Zhao, Zewen Zhuang, Xing Cao, Chao Zhang, Qing Peng, Chen Chen* and Yadong Li*, Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation, Chem. Soc. Rev., 2020, 49, 2215-2264.
7.Pengyu Song,# Botao Hu,# Di Zhao,* Jiantao Fu, Xiaoran Su, Wuyi Feng, Ke Yu, Shoujie Liu, Jiatao Zhang,* and Chen Chen,* Modulating the Asymmetric Atomic Interface of Copper Single Atoms for Efficient CO2 Electroreduction, ACS Nano 2023, 17, 5, 4619–4628.
8.Mengwei Li, Pengyu Song, Mengyun Hou, Wuyi Feng, Di Zhao,* Jiatao Zhang,* Atomic-level functionalized carbon-based materials for effective electrosynthesis of hydrogen peroxide: A review, Chem. Eng. J., 479, 147608.
9.Xiaoran Su, Caiyue Wang, Fang Zhao, Tianxin Wei, Di Zhao* and Jiatao Zhang,* Size effects of Supported Cu-based catalysts for electrocatalytic CO2 reduction reaction, J. Mater. Chem. A 2023, accepted.
10.Di Zhao,†,* Mengyun Hou,†, Wuyi Feng, Pengyu Song, Kaian Sun, Lirong Zheng, Shoujie Liu, Jiatao Zhang,* Minhua Cao,* Chen Chen,* Multi-interfacial Charge Polarization for Enhancing Hydrogen Evolution Reaction, Catalysis Science & Technology, 2023, 13, 4107.
11.Pan Zhu, Pengyu Song, Wuyi Feng, Di Zhao* Ting Liu, Jiatao Zhang* and Chen Chen,* Tailoring the Selectivity and Activity of Oxygen Reduction by Regulating the Coordination Environments of Carbon-Supported Atomically Dispersed Metal Sites, J. Mater. Chem. A, 2022, 10, 17948-17967.
12.Pengyu Song, Pan Zhu, Xiaoran Su, Mengyun Hou, Di Zhao,* and Jiatao Zhang,* Microenvironment Modulation in Carbon-Supported Single-Atom Catalysts for Efficient Electrocatalytic CO2 Reduction, CHEM-ASIAN J, 2022, e202200716.
13.Di Zhao, Jinwen Qin, Lirong Zheng, Donglei Guo, Jie Wang, and Minhua Cao*, Covalent interfacial coupling of vanadium nitride with nitrogenrich carbon textile boosting its lithium storage performance as binder-free anode, Nano Res., 2021, 14, 4336−4346.
14.Di Zhao, Ying Xiao, Xia Wang, Qing Gao, Minhua Cao,* Ultra-high lithium storage capacity achieved by porous ZnFe2O4/α-Fe2O3 micro-octahedrons, Nano Energy, 2014, 7, 124-133.
15.Di Zhao, Jinwen Qin, Lirong Zheng, and Minhua Cao*, Amorphous vanadium oxide/molybdenum oxide hybrid with three-dimensional ordered hierarchically porous structure as a high-performance li-ion battery anode, Chem. Mater. 2016, 28, 4180-4190.
16.Di Zhao, Mallory Clites, Guobing Ying, Sankalp Kota, Jie Wang, Varun Natu, Xin Wang, Ekaterina Pomerantseva, Minhua Cao* and Michel W. Barsoum*, Alkali-induced crumpling of Ti3C2Tx (MXene) to form 3D porous networks for sodium ion storage, Chem. Commun. 2018, 54, 4533-4536.
17.Di Zhao, Zhentao Cui, Shuguang Wang, Jinwen Qin and Minhua Cao* VN hollow spheres assembled from porous nanosheets for high-performance lithium storage and the oxygen reduction reaction, J. Mater. Chem. A, 2016, 4, 7914-7923.
18.Di Zhao, Lirong Zheng, Ying Xiao, Xia Wang, Minhua Cao,* Lithium storage in microstructures of amorphous mixed-valence vanadium oxide as anode materials, ChemSusChem, 2015, 8, 2212-222. (Cover paper)
19.Di Zhao, Minhua Cao,* Constructing highly graphitized carbon-wrapped Li3VO4 nanoparticles with hierarchically porous structure as a long life and high capacity anode for lithium-ion batteries, ACS Appl. Mater. Interfaces, 2015, 7, 25084-25093.
20.Di Zhao, Tao Meng, Jinwen Qin, Wei Wang, Zhigang Yin, and Minhua Cao,* Rational construction of multivoids-assembled hybrid nanospheres based on VPO4 encapsulated in porous carbon with superior lithium storage performance, ACS Appl. Mater. Interfaces, 2016, 9, 1437-1445.
21.Barsoum M W, Zhao D, Varun N. Crumpled mesoporous MXene powders synthesized by acid-, base-, or salt-induced crumpling: U.S. Patent 11,554,961[P]. 2023-1-17.
22.Barsoum M W, Zhao D, Varun N. Mesoporous MXene Powders Synthesized By Acid Or Base Induced Crumpling And Their Use As NA-Ion Battery Anodes: U.S. Patent Application 18/063,093[P]. 2023-4-27.