Zn2[(S)-O3PCH2NHC4H 7CO2]2: A homochiral 3D zinc phosphonate with helical channels

Xin Shi; Guangshan Zhu; Shilun Qiu; Kunlin Huang; Jihong Yu; Ruren Xu

doi:10.1002/anie.200460724

Zn₂[(S)-O₃PCH₂NHC₄H ₇CO₂]₂: A homochiral 3D zinc phosphonate with helical channels

Xin Shi^*, Guangshan Zhu, Shilun Qiu, Kunlin Huang, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

164 Citations (Scopus)

Abstract

Three types of channel - right- (R) and left-handed (L) helical, and achiral (A) - alternate along the c axis in the structure of the title compound (see picture). The catalytically active groups of the 1-phosphonomethylproline ligands are directed into the channels, thus suggesting applications of this material in asymmetric catalysis. (Figure presented).

Original language	English
Pages (from-to)	6482-6485
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	47
DOIs	https://doi.org/10.1002/anie.200460724
Publication status	Published - 3 Dec 2004
Externally published	Yes

Keywords

Amino acids
Helical structures
Hydrothermal synthesis
Zinc

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10.1002/anie.200460724

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Shi, X., Zhu, G., Qiu, S., Huang, K., Yu, J., & Xu, R. (2004). Zn₂[(S)-O₃PCH₂NHC₄H ₇CO₂]₂: A homochiral 3D zinc phosphonate with helical channels. Angewandte Chemie - International Edition, 43(47), 6482-6485. https://doi.org/10.1002/anie.200460724

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abstract = "Three types of channel - right- (R) and left-handed (L) helical, and achiral (A) - alternate along the c axis in the structure of the title compound (see picture). The catalytically active groups of the 1-phosphonomethylproline ligands are directed into the channels, thus suggesting applications of this material in asymmetric catalysis. (Figure presented).",

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T2 - A homochiral 3D zinc phosphonate with helical channels

AU - Shi, Xin

AU - Zhu, Guangshan

AU - Qiu, Shilun

AU - Huang, Kunlin

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2004/12/3

Y1 - 2004/12/3

N2 - Three types of channel - right- (R) and left-handed (L) helical, and achiral (A) - alternate along the c axis in the structure of the title compound (see picture). The catalytically active groups of the 1-phosphonomethylproline ligands are directed into the channels, thus suggesting applications of this material in asymmetric catalysis. (Figure presented).

AB - Three types of channel - right- (R) and left-handed (L) helical, and achiral (A) - alternate along the c axis in the structure of the title compound (see picture). The catalytically active groups of the 1-phosphonomethylproline ligands are directed into the channels, thus suggesting applications of this material in asymmetric catalysis. (Figure presented).

KW - Amino acids

KW - Helical structures

KW - Hydrothermal synthesis

KW - Zinc

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ER -

Zn₂[(S)-O₃PCH₂NHC₄H ₇CO₂]₂: A homochiral 3D zinc phosphonate with helical channels

Abstract

Keywords

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