Unique Cation Exchange in Nanocrystal Matrix via Surface Vacancy Engineering Overcoming Chemical Kinetic Energy Barriers

Bing Bai; Chongyang Zhao; Meng Xu; Jiabi Ma; Yijie Du; Hailong Chen; Jiajia Liu; Jia Liu; Hongpan Rong; Wenxing Chen; Yuxiang Weng; Sergio Brovelli; Jiatao Zhang

doi:10.1016/j.chempr.2020.08.020

Unique Cation Exchange in Nanocrystal Matrix via Surface Vacancy Engineering Overcoming Chemical Kinetic Energy Barriers

Bing Bai, Chongyang Zhao, Meng Xu^*, Jiabi Ma, Yijie Du, Hailong Chen, Jiajia Liu, Jia Liu, Hongpan Rong, Wenxing Chen, Yuxiang Weng, Sergio Brovelli, Jiatao Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Besides thermodynamic limitations, kinetic energy barriers hindered further exploration of synthesis mechanisms and functional nanomaterials. The breakthrough of kinetic energy barriers in cation exchange from CuInX₂ (X = S, Se) to Cu/In dual-doped CdX and ZnX SNCs was achieved unprecedentedly by an effective surface-vacancy-engineering-initialized cation exchange (SVEICE) strategy. The key of this strategy was sequentially creating Cu and In vacancies on multi-component SNC surfaces. In addition, this strategy possessed outstanding versatility in other multi-component SNC cation exchange processes.

Original language	English
Pages (from-to)	3086-3099
Number of pages	14
Journal	Chem
Volume	6
Issue number	11
DOIs	https://doi.org/10.1016/j.chempr.2020.08.020
Publication status	Published - 5 Nov 2020

Keywords

SDG9: Industry, innovation, and infrastructure
cation exchange
colloidal nanocrystals
doped quantum dots
kinetic energy barriers
surface defect engineering

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10.1016/j.chempr.2020.08.020

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title = "Unique Cation Exchange in Nanocrystal Matrix via Surface Vacancy Engineering Overcoming Chemical Kinetic Energy Barriers",

abstract = "Besides thermodynamic limitations, kinetic energy barriers hindered further exploration of synthesis mechanisms and functional nanomaterials. The breakthrough of kinetic energy barriers in cation exchange from CuInX2 (X = S, Se) to Cu/In dual-doped CdX and ZnX SNCs was achieved unprecedentedly by an effective surface-vacancy-engineering-initialized cation exchange (SVEICE) strategy. The key of this strategy was sequentially creating Cu and In vacancies on multi-component SNC surfaces. In addition, this strategy possessed outstanding versatility in other multi-component SNC cation exchange processes.",

keywords = "SDG9: Industry, innovation, and infrastructure, cation exchange, colloidal nanocrystals, doped quantum dots, kinetic energy barriers, surface defect engineering",

author = "Bing Bai and Chongyang Zhao and Meng Xu and Jiabi Ma and Yijie Du and Hailong Chen and Jiajia Liu and Jia Liu and Hongpan Rong and Wenxing Chen and Yuxiang Weng and Sergio Brovelli and Jiatao Zhang",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier Inc.",

year = "2020",

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doi = "10.1016/j.chempr.2020.08.020",

language = "English",

volume = "6",

pages = "3086--3099",

journal = "Chem",

issn = "2451-9308",

publisher = "Elsevier Inc.",

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TY - JOUR

T1 - Unique Cation Exchange in Nanocrystal Matrix via Surface Vacancy Engineering Overcoming Chemical Kinetic Energy Barriers

AU - Bai, Bing

AU - Zhao, Chongyang

AU - Xu, Meng

AU - Ma, Jiabi

AU - Du, Yijie

AU - Chen, Hailong

AU - Liu, Jiajia

AU - Liu, Jia

AU - Rong, Hongpan

AU - Chen, Wenxing

AU - Weng, Yuxiang

AU - Brovelli, Sergio

AU - Zhang, Jiatao

PY - 2020/11/5

Y1 - 2020/11/5

N2 - Besides thermodynamic limitations, kinetic energy barriers hindered further exploration of synthesis mechanisms and functional nanomaterials. The breakthrough of kinetic energy barriers in cation exchange from CuInX2 (X = S, Se) to Cu/In dual-doped CdX and ZnX SNCs was achieved unprecedentedly by an effective surface-vacancy-engineering-initialized cation exchange (SVEICE) strategy. The key of this strategy was sequentially creating Cu and In vacancies on multi-component SNC surfaces. In addition, this strategy possessed outstanding versatility in other multi-component SNC cation exchange processes.

AB - Besides thermodynamic limitations, kinetic energy barriers hindered further exploration of synthesis mechanisms and functional nanomaterials. The breakthrough of kinetic energy barriers in cation exchange from CuInX2 (X = S, Se) to Cu/In dual-doped CdX and ZnX SNCs was achieved unprecedentedly by an effective surface-vacancy-engineering-initialized cation exchange (SVEICE) strategy. The key of this strategy was sequentially creating Cu and In vacancies on multi-component SNC surfaces. In addition, this strategy possessed outstanding versatility in other multi-component SNC cation exchange processes.

KW - SDG9: Industry, innovation, and infrastructure

KW - cation exchange

KW - colloidal nanocrystals

KW - doped quantum dots

KW - kinetic energy barriers

KW - surface defect engineering

UR - http://www.scopus.com/inward/record.url?scp=85091916736&partnerID=8YFLogxK

U2 - 10.1016/j.chempr.2020.08.020

DO - 10.1016/j.chempr.2020.08.020

M3 - Article

AN - SCOPUS:85091916736

SN - 2451-9308

VL - 6

SP - 3086

EP - 3099

JO - Chem

JF - Chem

IS - 11

ER -

Unique Cation Exchange in Nanocrystal Matrix via Surface Vacancy Engineering Overcoming Chemical Kinetic Energy Barriers

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Keywords

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