Duan, H., Yan, N., Yu, R., Chang, C. R., Zhou, G., Hu, H. S., Rong, H., Niu, Z., Mao, J., Asakura, H., Tanaka, T., Dyson, P. J., Li, J., & Li, Y. (2014). Ultrathin rhodium nanosheets. Nature Communications, 5, Article 3093. https://doi.org/10.1038/ncomms4093
Duan, Haohong ; Yan, Ning ; Yu, Rong et al. / Ultrathin rhodium nanosheets. In: Nature Communications. 2014 ; Vol. 5.
@article{f09fbe72e0ae41be844a3c7dea664d3d,
title = "Ultrathin rhodium nanosheets",
abstract = "Despite significant advances in the fabrication and applications of graphene-like materials, it remains a challenge to prepare single-layered metallic materials, which have great potential applications in physics, chemistry and material science. Here we report the fabrication of poly(vinylpyrrolidone)-supported single-layered rhodium nanosheets using a facile solvothermal method. Atomic force microscope shows that the thickness of a rhodium nanosheet is <4 {\AA}. Electron diffraction and X-ray absorption spectroscopy measurements suggest that the rhodium nanosheets are composed of planar single-atom-layered sheets of rhodium. Density functional theory studies reveal that the single-layered Rh nanosheet involves a δ-bonding framework, which stabilizes the single-layered structure together with the poly(vinylpyrrolidone) ligands. The poly(vinylpyrrolidone)-supported single-layered rhodium nanosheet represents a class of metallic two-dimensional structures that might inspire further fundamental advances in physics, chemistry and material science.",
author = "Haohong Duan and Ning Yan and Rong Yu and Chang, {Chun Ran} and Gang Zhou and Hu, {Han Shi} and Hongpan Rong and Zhiqiang Niu and Junjie Mao and Hiroyuki Asakura and Tsunehiro Tanaka and Dyson, {Paul Joseph} and Jun Li and Yadong Li",
note = "Publisher Copyright: {\textcopyright} 2014 Macmillan Publishers Limited. All rights reserved.",
year = "2014",
month = jan,
day = "17",
doi = "10.1038/ncomms4093",
language = "English",
volume = "5",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Nature Publishing Group",
}
Duan, H, Yan, N, Yu, R, Chang, CR, Zhou, G, Hu, HS, Rong, H, Niu, Z, Mao, J, Asakura, H, Tanaka, T, Dyson, PJ, Li, J & Li, Y 2014, 'Ultrathin rhodium nanosheets', Nature Communications, vol. 5, 3093. https://doi.org/10.1038/ncomms4093
Ultrathin rhodium nanosheets. / Duan, Haohong; Yan, Ning; Yu, Rong et al.
In:
Nature Communications, Vol. 5, 3093, 17.01.2014.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Ultrathin rhodium nanosheets
AU - Duan, Haohong
AU - Yan, Ning
AU - Yu, Rong
AU - Chang, Chun Ran
AU - Zhou, Gang
AU - Hu, Han Shi
AU - Rong, Hongpan
AU - Niu, Zhiqiang
AU - Mao, Junjie
AU - Asakura, Hiroyuki
AU - Tanaka, Tsunehiro
AU - Dyson, Paul Joseph
AU - Li, Jun
AU - Li, Yadong
N1 - Publisher Copyright:
© 2014 Macmillan Publishers Limited. All rights reserved.
PY - 2014/1/17
Y1 - 2014/1/17
N2 - Despite significant advances in the fabrication and applications of graphene-like materials, it remains a challenge to prepare single-layered metallic materials, which have great potential applications in physics, chemistry and material science. Here we report the fabrication of poly(vinylpyrrolidone)-supported single-layered rhodium nanosheets using a facile solvothermal method. Atomic force microscope shows that the thickness of a rhodium nanosheet is <4 Å. Electron diffraction and X-ray absorption spectroscopy measurements suggest that the rhodium nanosheets are composed of planar single-atom-layered sheets of rhodium. Density functional theory studies reveal that the single-layered Rh nanosheet involves a δ-bonding framework, which stabilizes the single-layered structure together with the poly(vinylpyrrolidone) ligands. The poly(vinylpyrrolidone)-supported single-layered rhodium nanosheet represents a class of metallic two-dimensional structures that might inspire further fundamental advances in physics, chemistry and material science.
AB - Despite significant advances in the fabrication and applications of graphene-like materials, it remains a challenge to prepare single-layered metallic materials, which have great potential applications in physics, chemistry and material science. Here we report the fabrication of poly(vinylpyrrolidone)-supported single-layered rhodium nanosheets using a facile solvothermal method. Atomic force microscope shows that the thickness of a rhodium nanosheet is <4 Å. Electron diffraction and X-ray absorption spectroscopy measurements suggest that the rhodium nanosheets are composed of planar single-atom-layered sheets of rhodium. Density functional theory studies reveal that the single-layered Rh nanosheet involves a δ-bonding framework, which stabilizes the single-layered structure together with the poly(vinylpyrrolidone) ligands. The poly(vinylpyrrolidone)-supported single-layered rhodium nanosheet represents a class of metallic two-dimensional structures that might inspire further fundamental advances in physics, chemistry and material science.
UR - http://www.scopus.com/inward/record.url?scp=84901754555&partnerID=8YFLogxK
U2 - 10.1038/ncomms4093
DO - 10.1038/ncomms4093
M3 - Article
AN - SCOPUS:84901754555
SN - 2041-1723
VL - 5
JO - Nature Communications
JF - Nature Communications
M1 - 3093
ER -
Duan H, Yan N, Yu R, Chang CR, Zhou G, Hu HS et al. Ultrathin rhodium nanosheets. Nature Communications. 2014 Jan 17;5:3093. doi: 10.1038/ncomms4093
