TY - JOUR
T1 - Two photoluminescent coordination polymers based on naphthalene-1,4,5,8- tetracarboxylic acid 4,5-anhydride
AU - Xu, Yanqing
AU - Yuan, Daqiang
AU - Wu, Benlai
AU - Jiang, Feilong
AU - Zhou, Youfu
AU - Hong, Maochun
PY - 2005/7
Y1 - 2005/7
N2 - Two cadmium(II)-ntcaa coordination polymers, [Cd(phen)(ntcaa)(H 2O)2]n (1) and [Cd2(4,4′-bpy) (ntcaa)2]n (2) (ntcaa = naphthalene-1,4,5,8- tetracarboxylic acid 4,5-anhydride, phen = 1,10-phenanthroline, 4,4′-bpy = 4,4′-bipyridine), were synthesized via hydrothermal method. The structure of compound 1 is a neutral comb-like chain with π-π interactions between the phen and naphthalene aromatic rings, while that of 2 possesses an interesting baluster structure composed of helix chain as post and 4,4′-bpy as connector. Photoluminescent investigations reveal that both compounds exhibit strong emissions in the solid state.
AB - Two cadmium(II)-ntcaa coordination polymers, [Cd(phen)(ntcaa)(H 2O)2]n (1) and [Cd2(4,4′-bpy) (ntcaa)2]n (2) (ntcaa = naphthalene-1,4,5,8- tetracarboxylic acid 4,5-anhydride, phen = 1,10-phenanthroline, 4,4′-bpy = 4,4′-bipyridine), were synthesized via hydrothermal method. The structure of compound 1 is a neutral comb-like chain with π-π interactions between the phen and naphthalene aromatic rings, while that of 2 possesses an interesting baluster structure composed of helix chain as post and 4,4′-bpy as connector. Photoluminescent investigations reveal that both compounds exhibit strong emissions in the solid state.
KW - Cadmium
KW - Hydrothermal
KW - Naphthalene-1,4,5,8-tetracarboxylic acid 4,5-anhydride
KW - Photoluminescence
UR - http://www.scopus.com/inward/record.url?scp=20344401338&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2005.04.010
DO - 10.1016/j.inoche.2005.04.010
M3 - Article
AN - SCOPUS:20344401338
SN - 1387-7003
VL - 8
SP - 651
EP - 655
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 7
ER -