Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity

Li Li; Tan Su; Jiyang Li; Jin Xu; Jihong Yu; Ruren Xu

doi:10.1016/j.ica.2011.01.034

Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity

Li Li, Tan Su, Jiyang Li^*, Jin Xu, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two new bimetallic phosphates [(CH₃)₂NH] _0.5[Zn_0.62Co_0.38PO₃OH] (ZnCoPO-CJ48) and [(CH₃)₂NH₂][Zn_2.3Mn _0.7(PO₄)₂(PO₃OH)]·H ₃O (ZnMnPO-CJ49) have been solvothermally synthesized in the similar reaction system. ZnCoPO-CJ48 is a layered zinco-cobalt phosphate with neutral framework, its structure is constructed by the connection of Zn(Co)O₄ and PO₃OH tetrahedra forming a novel 2-D sheet with 3- and 4-rings. The alternating connection of Zn(Mn)O₄ and PO₄/PO ₃OH tetrahedra results in the open framework of ZnMnPO-CJ49 with 16-ring extra-large channels. Notably, both compounds are featured by the 4-ring building units T₂P₂O₆(OH)₂ formed by the connection of two TO₄ tetrahedra and two PO₃OH tetrahedra. The 3-D structure of ZnMnPO-CJ49 can be viewed as the connection of zinc-manganese phosphate layers analogous to the layered structure of ZnCoPO-CJ48 by the 1-D edge-sharing 4-ring chains as the pillars. In this work, the synthetic conditions of these two compounds and the influence of metal on the phase selectivity have been discussed in detail.

Original language	English
Pages (from-to)	65-69
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	370
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2011.01.034
Publication status	Published - 15 May 2011
Externally published	Yes

Keywords

Extra-large micropore
Heteroatom incorporation
Layered structure
Metal phosphate
Solvothermal synthesis

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10.1016/j.ica.2011.01.034

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@article{a0a8af9f95cd49e3bbf3c181307d605e,

title = "Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity",

abstract = "Two new bimetallic phosphates [(CH3)2NH] 0.5[Zn0.62Co0.38PO3OH] (ZnCoPO-CJ48) and [(CH3)2NH2][Zn2.3Mn 0.7(PO4)2(PO3OH)]·H 3O (ZnMnPO-CJ49) have been solvothermally synthesized in the similar reaction system. ZnCoPO-CJ48 is a layered zinco-cobalt phosphate with neutral framework, its structure is constructed by the connection of Zn(Co)O4 and PO3OH tetrahedra forming a novel 2-D sheet with 3- and 4-rings. The alternating connection of Zn(Mn)O4 and PO4/PO 3OH tetrahedra results in the open framework of ZnMnPO-CJ49 with 16-ring extra-large channels. Notably, both compounds are featured by the 4-ring building units T2P2O6(OH)2 formed by the connection of two TO4 tetrahedra and two PO3OH tetrahedra. The 3-D structure of ZnMnPO-CJ49 can be viewed as the connection of zinc-manganese phosphate layers analogous to the layered structure of ZnCoPO-CJ48 by the 1-D edge-sharing 4-ring chains as the pillars. In this work, the synthetic conditions of these two compounds and the influence of metal on the phase selectivity have been discussed in detail.",

keywords = "Extra-large micropore, Heteroatom incorporation, Layered structure, Metal phosphate, Solvothermal synthesis",

author = "Li Li and Tan Su and Jiyang Li and Jin Xu and Jihong Yu and Ruren Xu",

year = "2011",

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doi = "10.1016/j.ica.2011.01.034",

language = "English",

volume = "370",

pages = "65--69",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity

AU - Li, Li

AU - Su, Tan

AU - Li, Jiyang

AU - Xu, Jin

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2011/5/15

Y1 - 2011/5/15

N2 - Two new bimetallic phosphates [(CH3)2NH] 0.5[Zn0.62Co0.38PO3OH] (ZnCoPO-CJ48) and [(CH3)2NH2][Zn2.3Mn 0.7(PO4)2(PO3OH)]·H 3O (ZnMnPO-CJ49) have been solvothermally synthesized in the similar reaction system. ZnCoPO-CJ48 is a layered zinco-cobalt phosphate with neutral framework, its structure is constructed by the connection of Zn(Co)O4 and PO3OH tetrahedra forming a novel 2-D sheet with 3- and 4-rings. The alternating connection of Zn(Mn)O4 and PO4/PO 3OH tetrahedra results in the open framework of ZnMnPO-CJ49 with 16-ring extra-large channels. Notably, both compounds are featured by the 4-ring building units T2P2O6(OH)2 formed by the connection of two TO4 tetrahedra and two PO3OH tetrahedra. The 3-D structure of ZnMnPO-CJ49 can be viewed as the connection of zinc-manganese phosphate layers analogous to the layered structure of ZnCoPO-CJ48 by the 1-D edge-sharing 4-ring chains as the pillars. In this work, the synthetic conditions of these two compounds and the influence of metal on the phase selectivity have been discussed in detail.

AB - Two new bimetallic phosphates [(CH3)2NH] 0.5[Zn0.62Co0.38PO3OH] (ZnCoPO-CJ48) and [(CH3)2NH2][Zn2.3Mn 0.7(PO4)2(PO3OH)]·H 3O (ZnMnPO-CJ49) have been solvothermally synthesized in the similar reaction system. ZnCoPO-CJ48 is a layered zinco-cobalt phosphate with neutral framework, its structure is constructed by the connection of Zn(Co)O4 and PO3OH tetrahedra forming a novel 2-D sheet with 3- and 4-rings. The alternating connection of Zn(Mn)O4 and PO4/PO 3OH tetrahedra results in the open framework of ZnMnPO-CJ49 with 16-ring extra-large channels. Notably, both compounds are featured by the 4-ring building units T2P2O6(OH)2 formed by the connection of two TO4 tetrahedra and two PO3OH tetrahedra. The 3-D structure of ZnMnPO-CJ49 can be viewed as the connection of zinc-manganese phosphate layers analogous to the layered structure of ZnCoPO-CJ48 by the 1-D edge-sharing 4-ring chains as the pillars. In this work, the synthetic conditions of these two compounds and the influence of metal on the phase selectivity have been discussed in detail.

KW - Extra-large micropore

KW - Heteroatom incorporation

KW - Layered structure

KW - Metal phosphate

KW - Solvothermal synthesis

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U2 - 10.1016/j.ica.2011.01.034

DO - 10.1016/j.ica.2011.01.034

M3 - Article

AN - SCOPUS:79954601988

SN - 0020-1693

VL - 370

SP - 65

EP - 69

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity

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Keywords

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