Two-Dimensional Coordination Polymer Showing Spin-Crossover Behavior with a 64 K Wide Hysteresis Loop

Ya Nan Dong; Zhi Kun Liu; Jin Peng Xue; Yun Li; Ke Sun; Zi Shuo Yao; Jun Tao

doi:10.1021/acs.inorgchem.2c03626

Two-Dimensional Coordination Polymer Showing Spin-Crossover Behavior with a 64 K Wide Hysteresis Loop

Ya Nan Dong, Zhi Kun Liu, Jin Peng Xue, Yun Li, Ke Sun, Zi Shuo Yao^*, Jun Tao^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A two-dimensional grid-like coordination polymer, [Fe(NCBH₃)₂(Py₂ttz)₂]·4CHCl₃(1·4CHCl₃, Py₂ttz = 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole), showed one-step complete spin crossover with unexpectedly large hysteresis loop of 64 K wide and temperature-induced excited spin-state trapping effect below 91 K. copy; 2022 American Chemical Society.

Original language	English
Pages (from-to)	20232-20236
Number of pages	5
Journal	Inorganic Chemistry
Volume	61
Issue number	50
DOIs	https://doi.org/10.1021/acs.inorgchem.2c03626
Publication status	Published - 19 Dec 2022

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10.1021/acs.inorgchem.2c03626

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title = "Two-Dimensional Coordination Polymer Showing Spin-Crossover Behavior with a 64 K Wide Hysteresis Loop",

abstract = "A two-dimensional grid-like coordination polymer, [Fe(NCBH3)2(Py2ttz)2]·4CHCl3(1·4CHCl3, Py2ttz = 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole), showed one-step complete spin crossover with unexpectedly large hysteresis loop of 64 K wide and temperature-induced excited spin-state trapping effect below 91 K. copy; 2022 American Chemical Society.",

author = "Dong, {Ya Nan} and Liu, {Zhi Kun} and Xue, {Jin Peng} and Yun Li and Ke Sun and Yao, {Zi Shuo} and Jun Tao",

year = "2022",

month = dec,

day = "19",

doi = "10.1021/acs.inorgchem.2c03626",

language = "English",

volume = "61",

pages = "20232--20236",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "50",

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TY - JOUR

T1 - Two-Dimensional Coordination Polymer Showing Spin-Crossover Behavior with a 64 K Wide Hysteresis Loop

AU - Dong, Ya Nan

AU - Liu, Zhi Kun

AU - Xue, Jin Peng

AU - Li, Yun

AU - Sun, Ke

AU - Yao, Zi Shuo

AU - Tao, Jun

PY - 2022/12/19

Y1 - 2022/12/19

N2 - A two-dimensional grid-like coordination polymer, [Fe(NCBH3)2(Py2ttz)2]·4CHCl3(1·4CHCl3, Py2ttz = 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole), showed one-step complete spin crossover with unexpectedly large hysteresis loop of 64 K wide and temperature-induced excited spin-state trapping effect below 91 K. copy; 2022 American Chemical Society.

AB - A two-dimensional grid-like coordination polymer, [Fe(NCBH3)2(Py2ttz)2]·4CHCl3(1·4CHCl3, Py2ttz = 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole), showed one-step complete spin crossover with unexpectedly large hysteresis loop of 64 K wide and temperature-induced excited spin-state trapping effect below 91 K. copy; 2022 American Chemical Society.

UR - http://www.scopus.com/inward/record.url?scp=85143729317&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.2c03626

DO - 10.1021/acs.inorgchem.2c03626

M3 - Article

C2 - 36475660

AN - SCOPUS:85143729317

SN - 0020-1669

VL - 61

SP - 20232

EP - 20236

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 50

ER -

Two-Dimensional Coordination Polymer Showing Spin-Crossover Behavior with a 64 K Wide Hysteresis Loop

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