Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

Hailong Wang; Kang Wang; Jun Tao; Jianzhuang Jiang

doi:10.1039/c2cc16543k

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

Hailong Wang, Kang Wang, Jun Tao, Jianzhuang Jiang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

108 Citations (Scopus)

Abstract

Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.

Original language	English
Pages (from-to)	2973-2975
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	24
DOIs	https://doi.org/10.1039/c2cc16543k
Publication status	Published - 22 Feb 2012
Externally published	Yes

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title = "Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs",

abstract = "Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.",

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T1 - Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

AU - Wang, Hailong

AU - Wang, Kang

AU - Tao, Jun

AU - Jiang, Jianzhuang

PY - 2012/2/22

Y1 - 2012/2/22

N2 - Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.

AB - Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.

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U2 - 10.1039/c2cc16543k

DO - 10.1039/c2cc16543k

M3 - Article

AN - SCOPUS:84863115882

SN - 1359-7345

VL - 48

SP - 2973

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JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

Abstract

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