Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism

Nan Wang; Mingfeng Hu; Soren K. Mellerup; Xiang Wang; Françoise Sauriol; Tai Peng; Suning Wang

doi:10.1021/acs.inorgchem.7b01535

Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism

Nan Wang^*, Mingfeng Hu, Soren K. Mellerup, Xiang Wang, Françoise Sauriol, Tai Peng, Suning Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We report herein a series of triarylboron-functionalized Pt(II) dinuclear complexes using a photoactive bis(4-pyridyl)ethylene (bpe) bridging unit. The new Pt(II) complexes display phosphorescence at both room temperature and 77 K. Depending on the conditions under which crystals of the complexes were grown, either the cis- or trans-isomers could be obtained. The trans and cis isomers were found to undergo light-induced isomerization in solution with the trans isomer being the dominant species.

Original language	English
Pages (from-to)	12783-12794
Number of pages	12
Journal	Inorganic Chemistry
Volume	56
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.7b01535
Publication status	Published - 6 Nov 2017

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10.1021/acs.inorgchem.7b01535

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title = "Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism",

abstract = "We report herein a series of triarylboron-functionalized Pt(II) dinuclear complexes using a photoactive bis(4-pyridyl)ethylene (bpe) bridging unit. The new Pt(II) complexes display phosphorescence at both room temperature and 77 K. Depending on the conditions under which crystals of the complexes were grown, either the cis- or trans-isomers could be obtained. The trans and cis isomers were found to undergo light-induced isomerization in solution with the trans isomer being the dominant species.",

author = "Nan Wang and Mingfeng Hu and Mellerup, {Soren K.} and Xiang Wang and Fran{\c c}oise Sauriol and Tai Peng and Suning Wang",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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doi = "10.1021/acs.inorgchem.7b01535",

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T1 - Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand

T2 - Luminescence and Isomerism

AU - Wang, Nan

AU - Hu, Mingfeng

AU - Mellerup, Soren K.

AU - Wang, Xiang

AU - Sauriol, Françoise

AU - Peng, Tai

AU - Wang, Suning

PY - 2017/11/6

Y1 - 2017/11/6

N2 - We report herein a series of triarylboron-functionalized Pt(II) dinuclear complexes using a photoactive bis(4-pyridyl)ethylene (bpe) bridging unit. The new Pt(II) complexes display phosphorescence at both room temperature and 77 K. Depending on the conditions under which crystals of the complexes were grown, either the cis- or trans-isomers could be obtained. The trans and cis isomers were found to undergo light-induced isomerization in solution with the trans isomer being the dominant species.

AB - We report herein a series of triarylboron-functionalized Pt(II) dinuclear complexes using a photoactive bis(4-pyridyl)ethylene (bpe) bridging unit. The new Pt(II) complexes display phosphorescence at both room temperature and 77 K. Depending on the conditions under which crystals of the complexes were grown, either the cis- or trans-isomers could be obtained. The trans and cis isomers were found to undergo light-induced isomerization in solution with the trans isomer being the dominant species.

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U2 - 10.1021/acs.inorgchem.7b01535

DO - 10.1021/acs.inorgchem.7b01535

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SN - 0020-1669

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EP - 12794

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism

Abstract

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