TY - JOUR
T1 - Three complexes based on ligands 1-hydroxybenzotriazole and 1,4-benzenedicarboxylic acid
T2 - Synthesis, structures and luminescence properties
AU - Zhang, Zhong Qiang
AU - Huang, Ru Dan
AU - Xu, Yan Qing
AU - Yu, Li Qiong
AU - Jiao, Zhi Wei
AU - Zhu, Qin Lei
AU - Hu, Chang Wen
PY - 2009/12/1
Y1 - 2009/12/1
N2 - Three new complexes, [Mn(OBt)2(H2O)4]·3H2O (1) (OBt = 1-hydroxybenzotriazole ion), [Zn2(OBt)2(BDC)(H2O)·H2O]n (2) (H2BDC = 1,4-benzenedicarboxylic acid), and [Cu3(OBt)2(BDC)(μ3-OH)2(H2O)2·2H2O]n (3) were synthesized by hydrothermal method and were characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1, 2 and 3 are zero-dimensional (0D), two-dimensional (2D) and two-dimensional (2D) frameworks, respectively. In particular, there are all two crystallographically unique metal ions in the structures of complexes 2 and 3. Complex 2 possesses two helical chains in its structure. In the structure of 3, the chains that are built from tri-copper clusters and μ3-O atoms are connected with BDC2- to construct 2D grid structure. The luminescence properties of the three complexes were investigated.
AB - Three new complexes, [Mn(OBt)2(H2O)4]·3H2O (1) (OBt = 1-hydroxybenzotriazole ion), [Zn2(OBt)2(BDC)(H2O)·H2O]n (2) (H2BDC = 1,4-benzenedicarboxylic acid), and [Cu3(OBt)2(BDC)(μ3-OH)2(H2O)2·2H2O]n (3) were synthesized by hydrothermal method and were characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1, 2 and 3 are zero-dimensional (0D), two-dimensional (2D) and two-dimensional (2D) frameworks, respectively. In particular, there are all two crystallographically unique metal ions in the structures of complexes 2 and 3. Complex 2 possesses two helical chains in its structure. In the structure of 3, the chains that are built from tri-copper clusters and μ3-O atoms are connected with BDC2- to construct 2D grid structure. The luminescence properties of the three complexes were investigated.
KW - 1,4-Benzenedicarboxylic acid
KW - 1-Hydroxybenzotriazole
KW - Chemical synthesis
KW - Crystal structure
KW - Luminescence properties
UR - http://www.scopus.com/inward/record.url?scp=71749118742&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2009.09.031
DO - 10.1016/j.ica.2009.09.031
M3 - Article
AN - SCOPUS:71749118742
SN - 0020-1693
VL - 362
SP - 5183
EP - 5189
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 15
ER -