Thermoregulated phase-separable phosphine ruthenium complex for hydrogenation catalysis

Yanhua Wang; Xiaowei Wu; Fang Cheng; Zilin Jin

doi:10.1016/S1381-1169(02)00575-7

Thermoregulated phase-separable phosphine ruthenium complex for hydrogenation catalysis

Yanhua Wang, Xiaowei Wu, Fang Cheng, Zilin Jin^*

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Thermoregulated phase-separable Ru₃(CO)₁₂/PETPP (P-[p-C₆H₄O(CH₂CH₂O) _nH]₃, n = 6) complex was applied in the hydrogenation catalysis for the first time. With styrene as the model substrate, under the optimum conditions of P(H₂) = 2.0 MPa, T = 90 °C, the conversion of styrene and yield of ethylbenzene were 100 and 99.5%, respectively. After reaction, the catalyst could be easily separated from reaction mixture and reused for ten times without loss of activity has been observed.

Original language	English
Pages (from-to)	133-137
Number of pages	5
Journal	Journal of Molecular Catalysis A: Chemical
Volume	195
Issue number	1-2
DOIs	https://doi.org/10.1016/S1381-1169(02)00575-7
Publication status	Published - 18 Mar 2003
Externally published	Yes

Keywords

Hydrogenation
Nonionic phosphine ligand
Ru(CO)
Styrene
Thermoregulated phase-separable catalysis (TPSC)

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10.1016/S1381-1169(02)00575-7

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@article{54257e96eb8f483eb3e67f93af82a24b,

title = "Thermoregulated phase-separable phosphine ruthenium complex for hydrogenation catalysis",

abstract = "Thermoregulated phase-separable Ru3(CO)12/PETPP (P-[p-C6H4O(CH2CH2O) nH]3, n = 6) complex was applied in the hydrogenation catalysis for the first time. With styrene as the model substrate, under the optimum conditions of P(H2) = 2.0 MPa, T = 90 °C, the conversion of styrene and yield of ethylbenzene were 100 and 99.5%, respectively. After reaction, the catalyst could be easily separated from reaction mixture and reused for ten times without loss of activity has been observed.",

keywords = "Hydrogenation, Nonionic phosphine ligand, Ru(CO), Styrene, Thermoregulated phase-separable catalysis (TPSC)",

author = "Yanhua Wang and Xiaowei Wu and Fang Cheng and Zilin Jin",

year = "2003",

month = mar,

day = "18",

doi = "10.1016/S1381-1169(02)00575-7",

language = "English",

volume = "195",

pages = "133--137",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Thermoregulated phase-separable phosphine ruthenium complex for hydrogenation catalysis

AU - Wang, Yanhua

AU - Wu, Xiaowei

AU - Cheng, Fang

AU - Jin, Zilin

PY - 2003/3/18

Y1 - 2003/3/18

N2 - Thermoregulated phase-separable Ru3(CO)12/PETPP (P-[p-C6H4O(CH2CH2O) nH]3, n = 6) complex was applied in the hydrogenation catalysis for the first time. With styrene as the model substrate, under the optimum conditions of P(H2) = 2.0 MPa, T = 90 °C, the conversion of styrene and yield of ethylbenzene were 100 and 99.5%, respectively. After reaction, the catalyst could be easily separated from reaction mixture and reused for ten times without loss of activity has been observed.

AB - Thermoregulated phase-separable Ru3(CO)12/PETPP (P-[p-C6H4O(CH2CH2O) nH]3, n = 6) complex was applied in the hydrogenation catalysis for the first time. With styrene as the model substrate, under the optimum conditions of P(H2) = 2.0 MPa, T = 90 °C, the conversion of styrene and yield of ethylbenzene were 100 and 99.5%, respectively. After reaction, the catalyst could be easily separated from reaction mixture and reused for ten times without loss of activity has been observed.

KW - Hydrogenation

KW - Nonionic phosphine ligand

KW - Ru(CO)

KW - Styrene

KW - Thermoregulated phase-separable catalysis (TPSC)

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U2 - 10.1016/S1381-1169(02)00575-7

DO - 10.1016/S1381-1169(02)00575-7

M3 - Article

AN - SCOPUS:0037452822

SN - 1381-1169

VL - 195

SP - 133

EP - 137

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Thermoregulated phase-separable phosphine ruthenium complex for hydrogenation catalysis

Abstract

Keywords

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