Thermal reactions of YAlO 3 +. with methane: Increasing the reactivity of Y 2O 3 +. and the selectivity of Al 2O 3 +. by doping

Jia Bi Ma; Zhe Chen Wang; Maria Schlangen; Sheng Gui He; Helmut Schwarz

doi:10.1002/anie.201201698

Thermal reactions of YAlO ₃ ^+. with methane: Increasing the reactivity of Y ₂O ₃ ^+. and the selectivity of Al ₂O ₃ ^+. by doping

Jia Bi Ma^*, Zhe Chen Wang, Maria Schlangen, Sheng Gui He, Helmut Schwarz

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

HAT in hand: The heteronuclear oxide cluster YAlO ₃ ^+. exhibits higher reactivity and selectivity than Y ₂O ₃ ^+. and Al ₂O ₃ ^+., respectively, in the reaction with methane by hydrogen-atom transfer (HAT) at room temperature (see scheme).

Original language	English
Pages (from-to)	5991-5994
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	24
DOIs	https://doi.org/10.1002/anie.201201698
Publication status	Published - 11 Jun 2012
Externally published	Yes

Keywords

C-H activation
gas-phase reactions
mass spectrometry
radicals

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title = "Thermal reactions of YAlO 3 +. with methane: Increasing the reactivity of Y 2O 3 +. and the selectivity of Al 2O 3 +. by doping",

abstract = "HAT in hand: The heteronuclear oxide cluster YAlO 3 +. exhibits higher reactivity and selectivity than Y 2O 3 +. and Al 2O 3 +., respectively, in the reaction with methane by hydrogen-atom transfer (HAT) at room temperature (see scheme).",

keywords = "C-H activation, gas-phase reactions, mass spectrometry, radicals",

author = "Ma, {Jia Bi} and Wang, {Zhe Chen} and Maria Schlangen and He, {Sheng Gui} and Helmut Schwarz",

year = "2012",

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T1 - Thermal reactions of YAlO 3 +. with methane

T2 - Increasing the reactivity of Y 2O 3 +. and the selectivity of Al 2O 3 +. by doping

AU - Ma, Jia Bi

AU - Wang, Zhe Chen

AU - Schlangen, Maria

AU - He, Sheng Gui

AU - Schwarz, Helmut

PY - 2012/6/11

Y1 - 2012/6/11

N2 - HAT in hand: The heteronuclear oxide cluster YAlO 3 +. exhibits higher reactivity and selectivity than Y 2O 3 +. and Al 2O 3 +., respectively, in the reaction with methane by hydrogen-atom transfer (HAT) at room temperature (see scheme).

AB - HAT in hand: The heteronuclear oxide cluster YAlO 3 +. exhibits higher reactivity and selectivity than Y 2O 3 +. and Al 2O 3 +., respectively, in the reaction with methane by hydrogen-atom transfer (HAT) at room temperature (see scheme).

KW - C-H activation

KW - gas-phase reactions

KW - mass spectrometry

KW - radicals

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U2 - 10.1002/anie.201201698

DO - 10.1002/anie.201201698

M3 - Article

AN - SCOPUS:84861877058

SN - 1433-7851

VL - 51

SP - 5991

EP - 5994

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -

Thermal reactions of YAlO ₃ ^+. with methane: Increasing the reactivity of Y ₂O ₃ ^+. and the selectivity of Al ₂O ₃ ^+. by doping

Abstract

Keywords

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