Theoretical studies on nucleophilic vinylic halide substitution

Lin Jing Yang; Xiao Yuan Fu; Shao Wen Zhang

Theoretical studies on nucleophilic vinylic halide substitution

Lin Jing Yang, Xiao Yuan Fu, Shao Wen Zhang

Beijing Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of vinyl fluoride, chloride, bromide and iodide with CN^- and OH^- were studied. The trend of reactivity of vinyl halide with these two nucleophile is: fluoroethene<chloroethene ≈ bromoethene<iodoethene. The reaction of vinyl fluoride with CN^- tends to be a multi-step process while the reactions of the other three vinyl halides with CN^-, OH^- are all single-step processes. The nucleophilicity of CN^- is stronger than that of OH^-.

Original language	English
Pages (from-to)	631-634
Number of pages	4
Journal	Chinese Chemical Letters
Volume	7
Issue number	7
Publication status	Published - 1996
Externally published	Yes

Cite this

Yang, L. J., Fu, X. Y., & Zhang, S. W. (1996). Theoretical studies on nucleophilic vinylic halide substitution. Chinese Chemical Letters, 7(7), 631-634.

@article{f8edc50b4ecb4fc2aa60745299369db8,

title = "Theoretical studies on nucleophilic vinylic halide substitution",

abstract = "The reactions of vinyl fluoride, chloride, bromide and iodide with CN- and OH- were studied. The trend of reactivity of vinyl halide with these two nucleophile is: fluoroethene- tends to be a multi-step process while the reactions of the other three vinyl halides with CN-, OH- are all single-step processes. The nucleophilicity of CN- is stronger than that of OH-.",

author = "Yang, {Lin Jing} and Fu, {Xiao Yuan} and Zhang, {Shao Wen}",

year = "1996",

language = "English",

volume = "7",

pages = "631--634",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Theoretical studies on nucleophilic vinylic halide substitution

AU - Yang, Lin Jing

AU - Fu, Xiao Yuan

AU - Zhang, Shao Wen

PY - 1996

Y1 - 1996

N2 - The reactions of vinyl fluoride, chloride, bromide and iodide with CN- and OH- were studied. The trend of reactivity of vinyl halide with these two nucleophile is: fluoroethene- tends to be a multi-step process while the reactions of the other three vinyl halides with CN-, OH- are all single-step processes. The nucleophilicity of CN- is stronger than that of OH-.

AB - The reactions of vinyl fluoride, chloride, bromide and iodide with CN- and OH- were studied. The trend of reactivity of vinyl halide with these two nucleophile is: fluoroethene- tends to be a multi-step process while the reactions of the other three vinyl halides with CN-, OH- are all single-step processes. The nucleophilicity of CN- is stronger than that of OH-.

UR - http://www.scopus.com/inward/record.url?scp=3142643531&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:3142643531

SN - 1001-8417

VL - 7

SP - 631

EP - 634

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 7

ER -

Theoretical studies on nucleophilic vinylic halide substitution

Abstract

Other files and links

Fingerprint

Cite this