The synthesis of perfluoroamine using nitrogen trifluoride

Toshiyuki Takagi; Masanori Tamura; Motonari Shibakami; Heng Dao Quan; Akira Sekiya

doi:10.1016/S0022-1139(99)00191-8

The synthesis of perfluoroamine using nitrogen trifluoride

Toshiyuki Takagi^*, Masanori Tamura, Motonari Shibakami, Heng Dao Quan, Akira Sekiya

^*Corresponding author for this work

National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reactions of nitrogen trifluoride (1) with hexafluoropropene (2) in the presence of cesium fluoride (CsF) gave 2- (3) and 1-heptafluoropropyldifluoroamine (4) in moderate yields. Tetrafluoroethylene (6) and octafluoro-2-butene (8) similarly reacted with 1 to give corresponding products.

Original language	English
Pages (from-to)	15-17
Number of pages	3
Journal	Journal of Fluorine Chemistry
Volume	101
Issue number	1
DOIs	https://doi.org/10.1016/S0022-1139(99)00191-8
Publication status	Published - Jan 2000
Externally published	Yes

Keywords

Cesium fluoride
Fluoroamine
Hexafluoropropene
Nitrogen trifluoride
Octafluoro-2-butene
Tetrafluoroethylene

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10.1016/S0022-1139(99)00191-8

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title = "The synthesis of perfluoroamine using nitrogen trifluoride",

abstract = "The reactions of nitrogen trifluoride (1) with hexafluoropropene (2) in the presence of cesium fluoride (CsF) gave 2- (3) and 1-heptafluoropropyldifluoroamine (4) in moderate yields. Tetrafluoroethylene (6) and octafluoro-2-butene (8) similarly reacted with 1 to give corresponding products.",

keywords = "Cesium fluoride, Fluoroamine, Hexafluoropropene, Nitrogen trifluoride, Octafluoro-2-butene, Tetrafluoroethylene",

author = "Toshiyuki Takagi and Masanori Tamura and Motonari Shibakami and Quan, {Heng Dao} and Akira Sekiya",

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T1 - The synthesis of perfluoroamine using nitrogen trifluoride

AU - Takagi, Toshiyuki

AU - Tamura, Masanori

AU - Shibakami, Motonari

AU - Quan, Heng Dao

AU - Sekiya, Akira

PY - 2000/1

Y1 - 2000/1

N2 - The reactions of nitrogen trifluoride (1) with hexafluoropropene (2) in the presence of cesium fluoride (CsF) gave 2- (3) and 1-heptafluoropropyldifluoroamine (4) in moderate yields. Tetrafluoroethylene (6) and octafluoro-2-butene (8) similarly reacted with 1 to give corresponding products.

AB - The reactions of nitrogen trifluoride (1) with hexafluoropropene (2) in the presence of cesium fluoride (CsF) gave 2- (3) and 1-heptafluoropropyldifluoroamine (4) in moderate yields. Tetrafluoroethylene (6) and octafluoro-2-butene (8) similarly reacted with 1 to give corresponding products.

KW - Cesium fluoride

KW - Fluoroamine

KW - Hexafluoropropene

KW - Nitrogen trifluoride

KW - Octafluoro-2-butene

KW - Tetrafluoroethylene

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U2 - 10.1016/S0022-1139(99)00191-8

DO - 10.1016/S0022-1139(99)00191-8

M3 - Article

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SN - 0022-1139

VL - 101

SP - 15

EP - 17

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 1

ER -

The synthesis of perfluoroamine using nitrogen trifluoride

Abstract

Keywords

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